Bis{μ 2 -2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ 3 - N -methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κ N )dichromium(III)dimanganese(II) dimethylformamide tetrasolvate

The heterometallic title complex, [Cr2Mn2(C5H11NO2)2(C5H12NO2)2(NCS)4]·4C3H7NO, was prepared using manganese powder, Reineckes salt, ammonium thiocyanate and a non-aqueous solution of N-methyldiethanolamine in air. The centrosymmetric molecular structure of the complex is based on a tetranu...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-12, Vol.67 (12), p.m1864-m1865
Main Authors: Semenaka, Valentyna V., Nesterova, Oksana V., Kokozay, Volodymyr N., Zubatyuk, Roman I., Shishkin, Oleg V.
Format: Article
Language:English
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Summary:The heterometallic title complex, [Cr2Mn2(C5H11NO2)2(C5H12NO2)2(NCS)4]·4C3H7NO, was prepared using manganese powder, Reineckes salt, ammonium thiocyanate and a non-aqueous solution of N-methyldiethanolamine in air. The centrosymmetric molecular structure of the complex is based on a tetranuclear {Mn2Cr2(μ-O)6} core. The tetranuclear complex molecule and the two uncoordinated dimethylformamide molecules are linked by O—H...O hydrogen bonds, while the two other molecules of dimethylformamide do not participate in hydrogen bonding.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811049336