Tricyclo-[3.3.1.0]nonane-3,7-diyl bis-(methane-sulfonate)

The crystal structure of the title compound, C(11)H(18)O(6)S(2), was determined to investigate the effect of the eclipsed mesyl groups on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all lo...

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Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-01, Vol.66 (Pt 2), p.o409-o409
Main Authors: Ioannou, Savvas, Nicolaides, Athanassios V, Manos, Manolis J
Format: Article
Language:English
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Organic Papers
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Summary:The crystal structure of the title compound, C(11)H(18)O(6)S(2), was determined to investigate the effect of the eclipsed mesyl groups on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane [maximum deviation 0.01 Å], resulting in an eclipsing conformation of the C-O bonds. The C-C bond of the quaternary C atoms is 1.597 (3) Å is considerably longer than the other C-C bonds of the mol-ecule.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810001261