4-(4-Pyrid-yl)pyridinium perchlorate methanol solvate

In the cation of the title hydrated molecular salt, C(10)H(9)N(2) (+)·ClO(4) (-)·CH(3)OH, the dihedral angle formed by the pyridine rings is 28.82 (15)°. The crystal structure is stabilized by inter-molecular N-H⋯O and O-H⋯N hydrogen bonds and π-π stacking inter-actions, with centroid-to-centroid di...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-04, Vol.66 (Pt 5), p.o1068-o1068
Main Authors: Gao, Yu-Hua, Wu, De-Ming
Format: Article
Language:English
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Organic Papers
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Summary:In the cation of the title hydrated molecular salt, C(10)H(9)N(2) (+)·ClO(4) (-)·CH(3)OH, the dihedral angle formed by the pyridine rings is 28.82 (15)°. The crystal structure is stabilized by inter-molecular N-H⋯O and O-H⋯N hydrogen bonds and π-π stacking inter-actions, with centroid-to-centroid distances of 3.5913 (7) and 3.6526 (7) Å. Three O atoms of the perchlorate anion are disordered over two positions with refined occupancy factors of 0.649 (7):0.351 (7).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810012985