2-Hydroxy-3-(4-oxy(2,2,6,6-tetramethylpiperidin-1-oxyl)butoxy)benzaldehyde

Salen-type complexes with transition metals and corresponding polymers attract great scientific interest due to their high electrochemical properties and potential for use as part of next generation organic energy storage devices. Because of their good conductivity but relatively low capacity, energ...

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Bibliographic Details
Published in:MolBank 2021-09, Vol.2021 (3), p.M1245
Main Authors: Vereshchagin, Anatoliy A., Novoselova, Julia V., Kalnin, Arseniy Y., Lukyanov, Daniil A.
Format: Article
Language:English
Subjects:
Additives
Alkylation
Benzaldehyde
Conflicts of interest
Coordination compounds
Electrochemical analysis
Electrode materials
Energy storage
Fourier transforms
linkers
Mass spectrometry
NMR
Nuclear magnetic resonance
Polymers
Quinones
Research parks
Salen precursor
TEMPO
Transition metals
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Summary:Salen-type complexes with transition metals and corresponding polymers attract great scientific interest due to their high electrochemical properties and potential for use as part of next generation organic energy storage devices. Because of their good conductivity but relatively low capacity, energy-intensive additives such as quinones or TEMPO fragments can significantly enhance the capacitive characteristics of the electrode materials. Herein, we report a preparation of precursor for a modified Salen-type complex, the substituted 2,3-Dihydroxybenzaldehyde by butoxy linkers with TEMPO fragment using alkylation reaction. The resulting product was characterized by the 1H and 13C, COSY, HMBC, HSQC nuclear magnetic resonance (NMR), ESI–high resolution mass spectrometry (ESI–HRMS), and Fourier-transform infrared spectroscopy (FTIR). The reported approach opens the way for easy modification of Salen-type complexes in order to increase their specific characteristics.
ISSN:1422-8599
1422-8599
DOI:10.3390/M1245