Effect of sunset yellow dye on morphological, optical, dielectric, thermal and mechanical properties of KDP crystal

• Published in: Arabian journal of chemistry 2020-06, Vol.13 (6), p.5750-5764
• Main Authors: Sinha, Nidhi, Batra, Kriti, Bhukkal, Sumit, Kumar, Ranjan, Kumar, Sandeep, Goel, Sahil, Kumar, Binay
• Format: Article
• Language: English
• Subjects: Crystal morphology; Dye inclusion crystals; KDP crystal; Photoluminescence; Solid state absorption spectra; Sunset yellow dye
• ISSN: 1878-5352; 1878-5379
• DOI: 10.1016/j.arabjc.2020.04.013

[Display omitted] Herein, we describe the growth and morphology of well-defined dyed crystals of KH2PO4 (potassium dihydrogen orthophosphate; KDP) containing organic azo (sunset yellow; SSY) dye in the {1 0 1} & {0 0 1} pyramidal growth sectors. An understanding on selective dye inclusion in various growth sector of host crystal is proposed, which will help in designing novel tailor-made dyed photonic crystals. The structural analysis and the identification of various functional groups present in as grown KDP crystals were carried out using powder XRD, FTIR and Raman studies. Solid state transmittance spectra for dyed KDP crystals displayed three absorption peaks at 230 nm, 311 nm and 477 nm, which were blue shifted for SSY dye in KDP crystal relative to neutral aqueous solution of SSY dye. These blue shifts in the absorption maxima confirm the successful incorporation of sunset yellow dye into the pyramidal growth sectors of dyed KDP crystals. The band around 409 nm in the photoluminescence emission spectrum indicates a violet emission. SSY dye doped KDP crystals showed enhanced dielectric properties and thermal stability as compared to pure KDP crystal. The mechanical strength of the KDP crystals estimated using Vickers microhardness test was found to decrease with the increase in SSY dye doping.