Antifouling Membranes Prepared from Polyethersulfone Grafted with Poly(ethylene glycol) Methacrylate by Radiation-Induced Copolymerization in Homogeneous Solution

To synthesize evenly grafted copolymers, gamma radiation of homogeneous solutions was employed to graft poly­(ethylene glycol) methacrylate (PEGMA) onto polyethersulfone (PES). The grafting was verified by Fourier transform infrared spectroscopy, and the degrees of grafting (DGs) were determined by...

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Bibliographic Details
Published in:ACS omega 2020-10, Vol.5 (42), p.27094-27102
Main Authors: Lou, Dan, Hou, Zhengchi, Yang, Haijun, Liu, Yinfeng, Wang, Ting
Format: Article
Language:English
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Summary:To synthesize evenly grafted copolymers, gamma radiation of homogeneous solutions was employed to graft poly­(ethylene glycol) methacrylate (PEGMA) onto polyethersulfone (PES). The grafting was verified by Fourier transform infrared spectroscopy, and the degrees of grafting (DGs) were determined by elementary analysis. The PES-g-polyPEGMA copolymers with different DGs were obtained by changing the monomer concentration. Membranes were cast from pristine PES, PES/PEG blends, and PES-g-polyPEGMA with different DGs, respectively, via nonsolvent-induced phase separation. Results from water contact angle measurements and scanning electron microscopy analysis indicated that increasing DGs led to PES-g-polyPEGMA membranes with increasing hydrophilicity and porousness. Filtration experimental results showed that increasing DGs without adding pore-forming agents caused PES-g-polyPEGMA membranes with higher permeability. Compared with PES/PEG membranes with analogous permeation characteristics, in which PEG is added as a pore-forming agent, PES-g-polyPEGMA membranes exhibited superior antifouling properties.
ISSN:2470-1343
2470-1343
DOI:10.1021/acsomega.0c02439