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Atmosphere-Transported Emerging and Persistent Contaminants (EPCs) in Rainfall and Throughfall: Insights from a Rural Site in Northern Thailand
This study investigates the presence and concentrations of emerging and persistent contaminants (EPCs) in rainwater and throughfall water collected from urban areas and agricultural lands in northern Thailand. It focuses on one daily-use compound (caffeine), two industrial compounds (4-nitrophenol a...
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Published in: | Atmosphere 2023-10, Vol.14 (11), p.1603 |
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description | This study investigates the presence and concentrations of emerging and persistent contaminants (EPCs) in rainwater and throughfall water collected from urban areas and agricultural lands in northern Thailand. It focuses on one daily-use compound (caffeine), two industrial compounds (4-nitrophenol and tris(2-butoxyethyl) phosphate (TBEP)), and three agrichemicals (atrazine, fenobucarb, and 2,4-D). Additionally, information is provided regarding the presence of acetaminophen, fexofenadine, diphenhydramine, and gabapentin. Small differences in the chemical composition of the six main contaminants were observed between rainwater and forest throughfall water. However, significant variations were found in the concentration ranges of each EPC. In most cases, throughfall samples exhibited slightly higher concentrations, suggesting a limited contribution from dry deposition compared to rainfall. Limited reliable evidence was found concerning seasonal patterns in EPC concentrations in precipitation (rainfall and throughfall) and surface water samples in remote ponds and reservoirs. The transportation of EPCs via rainwater appears to vary among the compounds tested and is likely to vary from one rainfall event to another, rather than showing a strong and common seasonal response within the monsoon rainfall regime. These findings suggest that the transport of EPCs to remote areas via rainfall does occur for some EPCs. However, the dominance of this process over other transport mechanisms could not be determined with high confidence. |
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It focuses on one daily-use compound (caffeine), two industrial compounds (4-nitrophenol and tris(2-butoxyethyl) phosphate (TBEP)), and three agrichemicals (atrazine, fenobucarb, and 2,4-D). Additionally, information is provided regarding the presence of acetaminophen, fexofenadine, diphenhydramine, and gabapentin. Small differences in the chemical composition of the six main contaminants were observed between rainwater and forest throughfall water. However, significant variations were found in the concentration ranges of each EPC. In most cases, throughfall samples exhibited slightly higher concentrations, suggesting a limited contribution from dry deposition compared to rainfall. Limited reliable evidence was found concerning seasonal patterns in EPC concentrations in precipitation (rainfall and throughfall) and surface water samples in remote ponds and reservoirs. The transportation of EPCs via rainwater appears to vary among the compounds tested and is likely to vary from one rainfall event to another, rather than showing a strong and common seasonal response within the monsoon rainfall regime. These findings suggest that the transport of EPCs to remote areas via rainfall does occur for some EPCs. However, the dominance of this process over other transport mechanisms could not be determined with high confidence.</description><identifier>ISSN: 2073-4433</identifier><identifier>EISSN: 2073-4433</identifier><identifier>DOI: 10.3390/atmos14111603</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>2,4-D ; Acetaminophen ; Agricultural land ; Agriculture ; Agrochemicals ; Anthropocene ; Aquatic resources ; Atrazine ; Caffeine ; Chemical composition ; Composition ; Contaminants ; Contamination ; Diphenhydramine ; Distribution ; Dry deposition ; Dry season ; emerging contaminants ; Environmental aspects ; Environmental monitoring ; Fexofenadine ; Gabapentin ; Germany ; Herbicides ; Monsoon rainfall ; Nitrophenol ; p-Nitrophenol ; Personal grooming ; Pharmaceuticals ; Phosphates ; Pollutants ; Ponds ; Precipitation ; Rain ; Rain and rainfall ; Rain water ; Rain-water (Water-supply) ; Rainfall ; Rainfall regime ; Rainwater ; Rural areas ; Seasonal variations ; seasonality ; Surface water ; Thailand ; Throughfall ; Urban agriculture ; Urban areas ; Valsartan ; Water analysis ; Water sampling</subject><ispartof>Atmosphere, 2023-10, Vol.14 (11), p.1603</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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It focuses on one daily-use compound (caffeine), two industrial compounds (4-nitrophenol and tris(2-butoxyethyl) phosphate (TBEP)), and three agrichemicals (atrazine, fenobucarb, and 2,4-D). Additionally, information is provided regarding the presence of acetaminophen, fexofenadine, diphenhydramine, and gabapentin. Small differences in the chemical composition of the six main contaminants were observed between rainwater and forest throughfall water. However, significant variations were found in the concentration ranges of each EPC. In most cases, throughfall samples exhibited slightly higher concentrations, suggesting a limited contribution from dry deposition compared to rainfall. Limited reliable evidence was found concerning seasonal patterns in EPC concentrations in precipitation (rainfall and throughfall) and surface water samples in remote ponds and reservoirs. The transportation of EPCs via rainwater appears to vary among the compounds tested and is likely to vary from one rainfall event to another, rather than showing a strong and common seasonal response within the monsoon rainfall regime. These findings suggest that the transport of EPCs to remote areas via rainfall does occur for some EPCs. However, the dominance of this process over other transport mechanisms could not be determined with high confidence.</description><subject>2,4-D</subject><subject>Acetaminophen</subject><subject>Agricultural land</subject><subject>Agriculture</subject><subject>Agrochemicals</subject><subject>Anthropocene</subject><subject>Aquatic resources</subject><subject>Atrazine</subject><subject>Caffeine</subject><subject>Chemical composition</subject><subject>Composition</subject><subject>Contaminants</subject><subject>Contamination</subject><subject>Diphenhydramine</subject><subject>Distribution</subject><subject>Dry deposition</subject><subject>Dry season</subject><subject>emerging contaminants</subject><subject>Environmental aspects</subject><subject>Environmental monitoring</subject><subject>Fexofenadine</subject><subject>Gabapentin</subject><subject>Germany</subject><subject>Herbicides</subject><subject>Monsoon rainfall</subject><subject>Nitrophenol</subject><subject>p-Nitrophenol</subject><subject>Personal grooming</subject><subject>Pharmaceuticals</subject><subject>Phosphates</subject><subject>Pollutants</subject><subject>Ponds</subject><subject>Precipitation</subject><subject>Rain</subject><subject>Rain and rainfall</subject><subject>Rain water</subject><subject>Rain-water (Water-supply)</subject><subject>Rainfall</subject><subject>Rainfall regime</subject><subject>Rainwater</subject><subject>Rural areas</subject><subject>Seasonal variations</subject><subject>seasonality</subject><subject>Surface water</subject><subject>Thailand</subject><subject>Throughfall</subject><subject>Urban agriculture</subject><subject>Urban areas</subject><subject>Valsartan</subject><subject>Water analysis</subject><subject>Water sampling</subject><issn>2073-4433</issn><issn>2073-4433</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNptkk2P0zAQhiMEEqtlj9wtcYFDFn_GDbeqKlBpBauld2sST1JXiV1s98Cv4C_jbBGwErb8NXqf12Nrquo1o7dCtPQ95DkkJhljDRXPqitOtailFOL5P_uX1U1KR1qabAUX8qr6uV640wEj1vsIPp1CzGjJdsY4Oj8S8JbcY0wuZfSZbILPMDsPPifydnu_Se-I8-QBnB9gmh7l-0MM5_GwnD-QnU9uPBTxEMNMgDycI0zkm8u4cF_KbeVuXxhwU4FfVS8Kl_Dm93pd7T9u95vP9d3XT7vN-q7updC5bkEqvbKIVHe2AWVlNyiqAFANWmiue2XbHizlckDOB0mHRokOlLBoORfX1e5iawMczSm6GeIPE8CZx0CIo4GYXT-hEYKtugbaMqgUyDsFssy86S1vO2WL15uL1ymG72dM2RzDOfqSveGrlrdqpZn8qxqhmJbfCjlCP7vUm7XWUrCmYUtet_9RlW5xdn3wOLgSfwLUF6CPIaWIw5_HMGqWwjBPCkP8AoU7rBY</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Lee, Theodora H.Y</creator><creator>Srinuansom, Khajornkiat</creator><creator>Snyder, Shane A</creator><creator>Ziegler, Alan D</creator><general>MDPI AG</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7ST</scope><scope>7TG</scope><scope>7TN</scope><scope>7UA</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>H96</scope><scope>HCIFZ</scope><scope>KL.</scope><scope>L.G</scope><scope>PCBAR</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>SOI</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0003-2709-9840</orcidid></search><sort><creationdate>20231001</creationdate><title>Atmosphere-Transported Emerging and Persistent Contaminants (EPCs) in Rainfall and Throughfall: Insights from a Rural Site in Northern Thailand</title><author>Lee, Theodora H.Y ; 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It focuses on one daily-use compound (caffeine), two industrial compounds (4-nitrophenol and tris(2-butoxyethyl) phosphate (TBEP)), and three agrichemicals (atrazine, fenobucarb, and 2,4-D). Additionally, information is provided regarding the presence of acetaminophen, fexofenadine, diphenhydramine, and gabapentin. Small differences in the chemical composition of the six main contaminants were observed between rainwater and forest throughfall water. However, significant variations were found in the concentration ranges of each EPC. In most cases, throughfall samples exhibited slightly higher concentrations, suggesting a limited contribution from dry deposition compared to rainfall. Limited reliable evidence was found concerning seasonal patterns in EPC concentrations in precipitation (rainfall and throughfall) and surface water samples in remote ponds and reservoirs. The transportation of EPCs via rainwater appears to vary among the compounds tested and is likely to vary from one rainfall event to another, rather than showing a strong and common seasonal response within the monsoon rainfall regime. These findings suggest that the transport of EPCs to remote areas via rainfall does occur for some EPCs. However, the dominance of this process over other transport mechanisms could not be determined with high confidence.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/atmos14111603</doi><orcidid>https://orcid.org/0000-0003-2709-9840</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | 2,4-D Acetaminophen Agricultural land Agriculture Agrochemicals Anthropocene Aquatic resources Atrazine Caffeine Chemical composition Composition Contaminants Contamination Diphenhydramine Distribution Dry deposition Dry season emerging contaminants Environmental aspects Environmental monitoring Fexofenadine Gabapentin Germany Herbicides Monsoon rainfall Nitrophenol p-Nitrophenol Personal grooming Pharmaceuticals Phosphates Pollutants Ponds Precipitation Rain Rain and rainfall Rain water Rain-water (Water-supply) Rainfall Rainfall regime Rainwater Rural areas Seasonal variations seasonality Surface water Thailand Throughfall Urban agriculture Urban areas Valsartan Water analysis Water sampling |
title | Atmosphere-Transported Emerging and Persistent Contaminants (EPCs) in Rainfall and Throughfall: Insights from a Rural Site in Northern Thailand |
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