Structural, Dielectric and Electrical Properties of Modified BaTi0.80Fe0.20O3 Ceramics by Zr Addition in Ti Site at x=0.00 to 0.10

In this study we have synthesis the Zr substituted BaTi0.80Fe0.20O3 ceramics at different content of Zr from x=0.00 to 0.10 by using the solid-state route. The room temperature X-ray diffraction results confirmed the coexistence of the two tetragonal and hexagonal phases for x ≤ 0.050 of Zr content....

Full description

Saved in:
Bibliographic Details
Published in:Iranian journal materials science and engineering (Online) 2021-09, Vol.18 (3), p.1-12
Main Authors: Najwa Gouitaa, Lamcharfi Taj-dine, Abdi Farid, Ahjyaje Fatima Zahra
Format: Article
Language:English
Subjects:
anomalies
cole-cole
conductivity
dielectric permittivity
diffuse
raman
relaxation
solid-state
x-ray diffraction
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In this study we have synthesis the Zr substituted BaTi0.80Fe0.20O3 ceramics at different content of Zr from x=0.00 to 0.10 by using the solid-state route. The room temperature X-ray diffraction results confirmed the coexistence of the two tetragonal and hexagonal phases for x ≤ 0.050 of Zr content. While above 0.050 the hexagonal phase disappears in benefit of tetragonal phase. The Raman results confirmed the formation of these phases obtained with XRD. The scanning electron micrographs consist of both spherical and straight grain forms for x=0.000 to 0.075, and only spherical grain form for x=0.100 attributed to the tetragonal phase. Also, the grain size increases accompanied with a decrease in density of ceramics with increasing Zr content up to 0.050 then decreases accompanied with an increase in density. Detailed studies of dielectric permittivity measurement have provided a presence of two anomalies Te and TR-O at different temperatures, with a relaxation phenomenon and diffuse behavior which is very important for ceramic at x=0.075 of Zr content. The dielectric permittivity values of the two anomalies of Zr substituted BaTi0.80Fe0.20O3 ceramics increase with increase of Zr content and the dielectric loss is minimal at x=0.100 of Zr content. The conductivity increases with the increasing of Zr substitution from 0.025 to 0.075 levels while for x = 0.100 the dielectric conductivity decreases.  And the Cole-Cole analysis indicates a negative thermal resistivity coefficient (NTCR) behavior of these materials and an ideal Debye-type behavior.
ISSN:1735-0808
2383-3882
DOI:10.22068/ijmse.2059