Ag-Modified In₂O₃ Nanoparticles for Highly Sensitive and Selective Ethanol Alarming

• Published in: Sensors (Basel, Switzerland) Switzerland), 2017-09, Vol.17 (10), p.2220
• Main Authors: Wang, Jinxiao, Xie, Zheng, Si, Yuan, Liu, Xinyi, Zhou, Xinyuan, Yang, Jianfeng, Hu, Peng, Han, Ning, Yang, Jun, Chen, Yunfa
• Format: Article
• Language: English
• Subjects: Ag modification; Catalytic activity; Electron microscopy; Energy transmission; ethanol sensing; Gas sensors; heterojunction; Heterojunctions; high response; In2O3 nanoparticles; Indium oxides; Nanoparticles; Recovery time; Scanning electron microscopy; Silver; Spectrum analysis
• ISSN: 1424-8220; 1424-8220
• DOI: 10.3390/s17102220

Pure In₂O₃ nanoparticles are prepared by a facile precipitation method and are further modified by Ag. The synthesized samples are characterized by scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, Raman and UV-Vis spectra. The results show the successful heterojunction formation between Ag and In₂O₃. Gas sensing property measurements show that the 5 mol % Ag-modified In₂O₃ sensor has the response of 67 to 50 ppm ethanol, and fast response and recovery time of 22.3 and 11.7 s. The response is over one magnitude higher than that of pure In₂O₃, which can be attributed to the enhanced catalytic activity of Ag-modified In₂O₃ as compared with the pure one. The mechanism of the gas sensor can be explained by the spillover effect of Ag, which enhances the oxygen adsorption onto the surface of In₂O₃ and thus give rise to the higher activity and larger surface barrier height.