Spatial–temporal variations and process analysis of O3 pollution in Hangzhou during the G20 summit

• Published in: Atmospheric chemistry and physics 2020-05, Vol.20 (10), p.5963-5976
• Main Authors: Zhi-Zhen Ni, Luo, Kun, Gao, Yang, Gao, Xiang, Jiang, Fei, Huang, Cheng, Jian-Ren, Fan, Fu, Joshua S, Chang-Hong, Chen
• Format: Article
• Language: English
• Subjects: Advection; Air pollution; Atmospheric chemistry; Atmospheric processes; Boundary layers; Coal-fired power plants; Emission measurements; Emissions; Emissions control; Industrial plant emissions; Intercomparison; Mathematical models; Nitrogen compounds; Organic compounds; Outdoor air quality; Oxides; Ozone; Ozone concentration; Ozone formation; Parameters; Photochemical reactions; Photochemicals; Photochemistry; Planetary boundary layer; Pollutants; Pollution; Pollution monitoring; Simulation; Temporal variations; Vertical advection; Vertical diffusion; VOCs; Volatile organic compounds; Weather forecasting
• ISSN: 1680-7316; 1680-7324
• DOI: 10.5194/acp-20-5963-2020

Serious urban ozone (O3) pollution was observed during the campaign of 2016 G20 summit in Hangzhou, China, while other pollutants had been significantly reduced by the short-term emission control measures. To understand the underlying mechanism, the Weather Research Forecast with Chemistry (WRF-Chem) model is used to investigate the spatial and temporalO3 variations in Hangzhou from 24 August to 6 September 2016. The model is first successfully evaluated and validated for local and regional meteorological and chemical parameters by using the ground and upper-air level observed data. High ozone concentrations, temporally during most of the daytime emission control period and spatially from the surface to the top of the planetary boundary layer, are captured in Hangzhou and even the whole Yangtze River Delta region. Various atmospheric processes are further analyzed to determine the influential factors of local ozone formation through the integrated process rate method. Interesting horizontal and vertical advection circulations of O3 are observed during several short periods, and the effects of these processes are nearly canceled out. As a result, ozone pollution is mainly attributed to the local photochemical reactions that are not obviously influenced by the emission reduction measures. The ratio of reduction of Volatile Organic Compounds (VOCs) to that of NOx is a critical parameter that needs to be carefully considered for future alleviation of ozone formation. In addition, the vertical diffusion from the upper-air background O3 also plays an important role in shaping the surface ozone concentration. These results provide insight into urban O3 formation in Hangzhou and support the Model Intercomparison Study Asia Phase III (MICS-Asia Phase III).