Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigation

Nitrate in snow is subject to post-depositional processing, which leads to a net loss and redistribution within the snowpack. The relative importance of post-depositional loss processes such as the volatilization of nitric acid (HNO3) and photolysis of nitrate has long been debated. Changes in nitra...

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Bibliographic Details
Published in:Polar research 2020-12, Vol.39, p.1-9
Main Authors: Noro, Kazushi, Takenaka, Norimichi
Format: Article
Language:English
Subjects:
antarctica
Chloride ions
Chlorides
Chromatography
Field investigations
Geochemical cycle
Geochemical cycles
Homogenization
Hydrochloric acid
Ice
Laboratories
Net losses
Nitrates
Nitric acid
Nitric acids
nitrogen cycle
nitrogen oxides
ozone
Photolysis
Snow
Snowpack
Soil sciences
Sublimation
Volatilization
Water vapor
Water vapour
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Summary:Nitrate in snow is subject to post-depositional processing, which leads to a net loss and redistribution within the snowpack. The relative importance of post-depositional loss processes such as the volatilization of nitric acid (HNO3) and photolysis of nitrate has long been debated. Changes in nitrate and chloride concentrations in the snowpack were investigated at H128 (69°23.584’S, 41°33.712’E), an Antarctic coastal site approximately 100 km from Syowa Station in East Antarctica from December 2015 to February 2016. Results indicate that chloride migrated to deeper sites within the snowpack under the influence of water vapour movement. Moreover, 50% of the nitrate on surface snow was lost to photolysis, and approximately 20% of the nitrate was absent at a depth of 40 cm. To enhance our knowledge of the Antarctic geochemical cycle, this study is the first to suggest chloride ion movement in snowpacks or significant nitrate loss for any Antarctic coastal site.
ISSN:0800-0395
1751-8369
DOI:10.33265/polar.v39.5146