Tetrakis(1-ethyl-1 H -imidazole-κ N 3 )bis(thiocyanato-κ N )cadmium(II)

The structure of the title compound, [Cd(NCS)2(C5H8N2)4], consists of isolated molecules of [Cd(NCS)2(Eim)4] (Eim = 1-ethylimidazole), which contain a compressed octahedral CdN6 chromophore. The NCS− anions are trans and four N atoms from the 1-ethylimidazole ligands define the equatorial...

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Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-03, Vol.66 (3), p.m290-m290
Main Authors: Li, Rong-Xun, Wu, Qi-Ye, Liu, Fa-Qian
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description The structure of the title compound, [Cd(NCS)2(C5H8N2)4], consists of isolated molecules of [Cd(NCS)2(Eim)4] (Eim = 1-ethylimidazole), which contain a compressed octahedral CdN6 chromophore. The NCS− anions are trans and four N atoms from the 1-ethylimidazole ligands define the equatorial plane. The mean Cd—N(Eim) and Cd—N(NCS) distances are 2.334 (4) and 2.379 (5) Å, respectively. Weak C—H...N interactions contribute to the crystal packing stability.
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title Tetrakis(1-ethyl-1 H -imidazole-κ N 3 )bis(thiocyanato-κ N )cadmium(II)
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