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The Anion–Cation Relay Battery Prototype
Relay insertion/extraction chemistry of both anions and cations on the cathode is disclosed for non‐aqueous rechargeable batteries, different from previous metal‐ion batteries (MIBs) and dual‐ion batteries (DIBs) of only positively or negatively charged ions. The “anion–cation relay battery (ACRB)”...
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Published in: | Small science 2021-01, Vol.1 (1), p.n/a |
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description | Relay insertion/extraction chemistry of both anions and cations on the cathode is disclosed for non‐aqueous rechargeable batteries, different from previous metal‐ion batteries (MIBs) and dual‐ion batteries (DIBs) of only positively or negatively charged ions. The “anion–cation relay battery (ACRB)” fully uses both negative and positive ions and offers bright prospects for high‐specific‐energy and large‐rate grid scale energy storage. Proof‐of‐concept ACRBs with commercial Li/Na/K plate as anodes and free‐standing few‐layered graphitic carbon (FLGC) membrane as cathodes demonstrate impressive overall cell performance (a reversible capacity of ≈300 mAh g−1 at 100 mA g−1, service life >23 000 cycles with a retention decay of ≈0.0013% per cycle, and a cathode energy density of ≈370 Wh kg−1 at ≈27 kW kg−1), comparable to the highest level counterparts. The work may set a promising strategy to break the predicament facing by various MIBs and DIBs, and also a direction to forward cost cutting in commercial lithium‐ion batteries (LIBs).
The basic concepts and working mechanism of anion–cation relay battery prototype are established. This type of battery offers bright prospects for high‐specific‐energy and large‐rate grid scale energy storage by relay insertion/extraction chemistry of both anions and cations on the cathode. The exemplified batteries demonstrate impressive overall performance, comparable to the most advanced counterparts. |
doi_str_mv | 10.1002/smsc.202000030 |
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The basic concepts and working mechanism of anion–cation relay battery prototype are established. This type of battery offers bright prospects for high‐specific‐energy and large‐rate grid scale energy storage by relay insertion/extraction chemistry of both anions and cations on the cathode. The exemplified batteries demonstrate impressive overall performance, comparable to the most advanced counterparts.</description><identifier>ISSN: 2688-4046</identifier><identifier>EISSN: 2688-4046</identifier><identifier>DOI: 10.1002/smsc.202000030</identifier><language>eng</language><publisher>Wiley-VCH</publisher><subject>anion–cation ; high energy/power ; membranes ; rechargeable batteries ; relay insertion/extraction</subject><ispartof>Small science, 2021-01, Vol.1 (1), p.n/a</ispartof><rights>2020 The Authors. Published by Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3950-3be885d711d35a7f7a0291cadf0417322ad0b131e169df0596de91457e21e0b83</citedby><cites>FETCH-LOGICAL-c3950-3be885d711d35a7f7a0291cadf0417322ad0b131e169df0596de91457e21e0b83</cites><orcidid>0000-0001-9091-2297 ; 0000-0001-8355-6431 ; 0000-0003-0239-1351</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fsmsc.202000030$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fsmsc.202000030$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,11562,27924,27925,46052,46476</link.rule.ids></links><search><creatorcontrib>Song, Huawei</creatorcontrib><creatorcontrib>Su, Jian</creatorcontrib><creatorcontrib>Wang, Chengxin</creatorcontrib><title>The Anion–Cation Relay Battery Prototype</title><title>Small science</title><description>Relay insertion/extraction chemistry of both anions and cations on the cathode is disclosed for non‐aqueous rechargeable batteries, different from previous metal‐ion batteries (MIBs) and dual‐ion batteries (DIBs) of only positively or negatively charged ions. The “anion–cation relay battery (ACRB)” fully uses both negative and positive ions and offers bright prospects for high‐specific‐energy and large‐rate grid scale energy storage. Proof‐of‐concept ACRBs with commercial Li/Na/K plate as anodes and free‐standing few‐layered graphitic carbon (FLGC) membrane as cathodes demonstrate impressive overall cell performance (a reversible capacity of ≈300 mAh g−1 at 100 mA g−1, service life >23 000 cycles with a retention decay of ≈0.0013% per cycle, and a cathode energy density of ≈370 Wh kg−1 at ≈27 kW kg−1), comparable to the highest level counterparts. The work may set a promising strategy to break the predicament facing by various MIBs and DIBs, and also a direction to forward cost cutting in commercial lithium‐ion batteries (LIBs).
The basic concepts and working mechanism of anion–cation relay battery prototype are established. This type of battery offers bright prospects for high‐specific‐energy and large‐rate grid scale energy storage by relay insertion/extraction chemistry of both anions and cations on the cathode. The exemplified batteries demonstrate impressive overall performance, comparable to the most advanced counterparts.</description><subject>anion–cation</subject><subject>high energy/power</subject><subject>membranes</subject><subject>rechargeable batteries</subject><subject>relay insertion/extraction</subject><issn>2688-4046</issn><issn>2688-4046</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>DOA</sourceid><recordid>eNqFkM1OwzAQhC0EElXplXPOSCle24ntY4n4qVQEouVsufEGUqV1ZUdCufEOvCFPQkpR4cZedjSa-Q5DyDnQMVDKLuM6lmNGGe2P0yMyYLlSqaAiP_6jT8koxlUfYRmA1GxALhavmEw2td98vn8Utu1F8oSN7ZIr27YYuuQx-Na33RbPyEllm4ijnz8kzzfXi-IunT3cTovJLC25zmjKl6hU5iSA45mVlbSUaSitq6gAyRmzji6BA0Kuey_TuUMNIpPIAOlS8SGZ7rnO25XZhnptQ2e8rc234cOLsaGtywYNR8aBMi5FDxeV0FY5xXINXDoFuGON96wy-BgDVgceULMbzuyGM4fh-oLeF97qBrt_0mZ-Py9-u18U52_A</recordid><startdate>202101</startdate><enddate>202101</enddate><creator>Song, Huawei</creator><creator>Su, Jian</creator><creator>Wang, Chengxin</creator><general>Wiley-VCH</general><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0001-9091-2297</orcidid><orcidid>https://orcid.org/0000-0001-8355-6431</orcidid><orcidid>https://orcid.org/0000-0003-0239-1351</orcidid></search><sort><creationdate>202101</creationdate><title>The Anion–Cation Relay Battery Prototype</title><author>Song, Huawei ; Su, Jian ; Wang, Chengxin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3950-3be885d711d35a7f7a0291cadf0417322ad0b131e169df0596de91457e21e0b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>anion–cation</topic><topic>high energy/power</topic><topic>membranes</topic><topic>rechargeable batteries</topic><topic>relay insertion/extraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Song, Huawei</creatorcontrib><creatorcontrib>Su, Jian</creatorcontrib><creatorcontrib>Wang, Chengxin</creatorcontrib><collection>Wiley Open Access</collection><collection>Wiley Online Library website</collection><collection>CrossRef</collection><collection>Directory of Open Access Journals</collection><jtitle>Small science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Song, Huawei</au><au>Su, Jian</au><au>Wang, Chengxin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Anion–Cation Relay Battery Prototype</atitle><jtitle>Small science</jtitle><date>2021-01</date><risdate>2021</risdate><volume>1</volume><issue>1</issue><epage>n/a</epage><issn>2688-4046</issn><eissn>2688-4046</eissn><abstract>Relay insertion/extraction chemistry of both anions and cations on the cathode is disclosed for non‐aqueous rechargeable batteries, different from previous metal‐ion batteries (MIBs) and dual‐ion batteries (DIBs) of only positively or negatively charged ions. The “anion–cation relay battery (ACRB)” fully uses both negative and positive ions and offers bright prospects for high‐specific‐energy and large‐rate grid scale energy storage. Proof‐of‐concept ACRBs with commercial Li/Na/K plate as anodes and free‐standing few‐layered graphitic carbon (FLGC) membrane as cathodes demonstrate impressive overall cell performance (a reversible capacity of ≈300 mAh g−1 at 100 mA g−1, service life >23 000 cycles with a retention decay of ≈0.0013% per cycle, and a cathode energy density of ≈370 Wh kg−1 at ≈27 kW kg−1), comparable to the highest level counterparts. The work may set a promising strategy to break the predicament facing by various MIBs and DIBs, and also a direction to forward cost cutting in commercial lithium‐ion batteries (LIBs).
The basic concepts and working mechanism of anion–cation relay battery prototype are established. This type of battery offers bright prospects for high‐specific‐energy and large‐rate grid scale energy storage by relay insertion/extraction chemistry of both anions and cations on the cathode. The exemplified batteries demonstrate impressive overall performance, comparable to the most advanced counterparts.</abstract><pub>Wiley-VCH</pub><doi>10.1002/smsc.202000030</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-9091-2297</orcidid><orcidid>https://orcid.org/0000-0001-8355-6431</orcidid><orcidid>https://orcid.org/0000-0003-0239-1351</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | anion–cation high energy/power membranes rechargeable batteries relay insertion/extraction |
title | The Anion–Cation Relay Battery Prototype |
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