Facile Fabrication of an Ammonia-Gas Sensor Using Electrochemically Synthesised Polyaniline on Commercial Screen-Printed Three-Electrode Systems

• Published in: Sensors (Basel, Switzerland) Switzerland), 2021-01, Vol.21 (1), p.169
• Main Authors: Korent, Anja, Žagar Soderžnik, Kristina, Šturm, Sašo, Žužek Rožman, Kristina, Redon, Nathalie, Wojkiewicz, Jean-Luc, Duc, Caroline
• Format: Article
• Language: English
• Subjects: Ammonia; Chemical Sciences; Conducting polymers; cyclic voltammetry (CV); Electrodes; Electrolytes; electropolymerisation; Engineering Sciences; Environmental Engineering; Environmental Sciences; Feasibility; Gas analyzers; Gas sensors; Gases; Glass substrates; Humidity; Materials; Metal oxides; Micro and nanotechnologies; Microelectronics; Morphology; Nanomaterials; NH3 detection; polyaniline (PANI); Polyanilines; Polymers; screen-printed electrode (SPE); Sensors
• ISSN: 1424-8220; 1424-8220
• DOI: 10.3390/s21010169

Polyaniline (PANI) is a conducting polymer, widely used in gas-sensing applications. Due to its classification as a semiconductor, PANI is also used to detect reducing ammonia gas (NH ), which is a well-known and studied topic. However, easier, cheaper and more straightforward procedures for sensor fabrication are still the subject of much research. In the presented work, we describe a novel, more controllable, synthesis approach to creating NH PANI-based receptor elements. The PANI was electrochemically deposited via cyclic voltammetry (CV) on screen-printed electrodes (SPEs). The morphology, composition and surface of the deposited PANI layer on the Au electrode were characterised with electron microscopy, Fourier-transform infrared spectroscopy and profilometry. Prior to the gas-chamber measurement, the SPE was suitably modified by Au sputtering the individual connections between the three-electrode system, thus showing a feasible way of converting a conventional three-electrode electrochemical SPE system into a two-electrode NH -gas detecting system. The feasibility of the gas measurements' characterisation was improved using the gas analyser. The gas-sensing ability of the PANI-Au-SPE was studied in the range 32-1100 ppb of NH , and the sensor performed well in terms of repeatability, reproducibility and sensitivity.