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Substitution of Pb with (Li1∕2Bi1∕2) in PbZrO3-based antiferroelectric ceramics
PbZrO3-based antiferroelectric (AFE) ceramics are promising dielectrics for high-energy-density capacitors due to their reversible phase transitions during charge–discharge cycles. In this work, a new composition series, [Pb 0 . 9 3 − x La 0 . 0 2 (Li 1 ∕ 2 Bi 1 ∕ 2 ) x Sr 0 . 0 4 ][Zr 0 . 5 7 Sn 0...
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| Published in: | Journal of advanced dielectrics 2024-02, Vol.14 (1) |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| container_title | Journal of advanced dielectrics |
| container_volume | 14 |
| creator | Liu, Binzhi Gaur, Anand P. S. Cui, Jun Tan, Xiaoli |
| description | PbZrO3-based antiferroelectric (AFE) ceramics are promising dielectrics for high-energy-density capacitors due to their reversible phase transitions during charge–discharge cycles. In this work, a new composition series, [Pb
0
.
9
3
−
x
La
0
.
0
2
(Li
1
∕
2
Bi
1
∕
2
)
x
Sr
0
.
0
4
][Zr
0
.
5
7
Sn
0
.
3
4
Ti
0
.
0
9
]O3, with Li
+
and Bi
3
+
substitution of Pb
2
+
at
x
=
0
, 0.04, 0.08, 0.12, 0.16 is investigated for the microstructure evolution, ferroelectric (FE) and dielectric properties. It is found that Li
+
and Bi
3
+
substitution can significantly reduce the sintering temperature and simultaneously enhance the dielectric breakdown strength. An ultrahigh energy efficiency (94.0%) and a large energy density (3.22
J/cm
3
)
are achieved in the composition of
x
=
0
.
1
2
with a low sintering temperature (1075∘C). |
| doi_str_mv | 10.1142/S2010135X23500224 |
| format | article |
| fullrecord | <record><control><sourceid>doaj_world</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_3f5a1a5fc5a04134991b3ff2ef95078c</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_3f5a1a5fc5a04134991b3ff2ef95078c</doaj_id><sourcerecordid>oai_doaj_org_article_3f5a1a5fc5a04134991b3ff2ef95078c</sourcerecordid><originalsourceid>FETCH-LOGICAL-d3054-c8f7625233ea57b857587454672592aed2f8d5707db7afab4c0cfb790e57a0953</originalsourceid><addsrcrecordid>eNplkE1KA0EQhRtRMGgO4G6Wuhit_qn0zFKDP4FAhCgEN0P1n3aYZKRnQvAGXsALehITI9n4Nu_xCj6ox9gZh0vOlbiaCuDAJc6ERAAh1AHrbaucy0FxuM84O2b9tp3DRogFSOyx6XRl2i52qy42y6wJ2aPJ1rF7y87HkX9_fombnV1kcbm5vaSJzA213mW07GLwKTW-9rZL0WbWJ1pE256yo0B16_t_fsKe726fhg_5eHI_Gl6PcycBVW6LoAcChZSeUJsCNRZaoRpogaUg70QoHGrQzmgKZJQFG4wuwaMmKFGesNGO6xqaV-8pLih9VA3F6rdo0mtFqYu29pUMSJwwWCRQXKqy5EaGIHwoEXRhNyzYsdZNql1ro9--F-0e-29j-QPowW9y</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Substitution of Pb with (Li1∕2Bi1∕2) in PbZrO3-based antiferroelectric ceramics</title><source>World Scientific Journals</source><creator>Liu, Binzhi ; Gaur, Anand P. S. ; Cui, Jun ; Tan, Xiaoli</creator><creatorcontrib>Liu, Binzhi ; Gaur, Anand P. S. ; Cui, Jun ; Tan, Xiaoli</creatorcontrib><description>PbZrO3-based antiferroelectric (AFE) ceramics are promising dielectrics for high-energy-density capacitors due to their reversible phase transitions during charge–discharge cycles. In this work, a new composition series, [Pb
0
.
9
3
−
x
La
0
.
0
2
(Li
1
∕
2
Bi
1
∕
2
)
x
Sr
0
.
0
4
][Zr
0
.
5
7
Sn
0
.
3
4
Ti
0
.
0
9
]O3, with Li
+
and Bi
3
+
substitution of Pb
2
+
at
x
=
0
, 0.04, 0.08, 0.12, 0.16 is investigated for the microstructure evolution, ferroelectric (FE) and dielectric properties. It is found that Li
+
and Bi
3
+
substitution can significantly reduce the sintering temperature and simultaneously enhance the dielectric breakdown strength. An ultrahigh energy efficiency (94.0%) and a large energy density (3.22
J/cm
3
)
are achieved in the composition of
x
=
0
.
1
2
with a low sintering temperature (1075∘C).</description><identifier>ISSN: 2010-135X</identifier><identifier>EISSN: 2010-1368</identifier><identifier>DOI: 10.1142/S2010135X23500224</identifier><language>eng</language><publisher>World Scientific Publishing Company</publisher><subject>energy efficiency ; energy storage ; LiBi substitution ; PbZrO3-based antiferroelectrics</subject><ispartof>Journal of advanced dielectrics, 2024-02, Vol.14 (1)</ispartof><rights>2024, The Author(s)</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.worldscientific.com/doi/reader/10.1142/S2010135X23500224$$EPDF$$P50$$Gworldscientific$$Hfree_for_read</linktopdf><link.rule.ids>314,780,784,4872,27924,27925,55587</link.rule.ids></links><search><creatorcontrib>Liu, Binzhi</creatorcontrib><creatorcontrib>Gaur, Anand P. S.</creatorcontrib><creatorcontrib>Cui, Jun</creatorcontrib><creatorcontrib>Tan, Xiaoli</creatorcontrib><title>Substitution of Pb with (Li1∕2Bi1∕2) in PbZrO3-based antiferroelectric ceramics</title><title>Journal of advanced dielectrics</title><description>PbZrO3-based antiferroelectric (AFE) ceramics are promising dielectrics for high-energy-density capacitors due to their reversible phase transitions during charge–discharge cycles. In this work, a new composition series, [Pb
0
.
9
3
−
x
La
0
.
0
2
(Li
1
∕
2
Bi
1
∕
2
)
x
Sr
0
.
0
4
][Zr
0
.
5
7
Sn
0
.
3
4
Ti
0
.
0
9
]O3, with Li
+
and Bi
3
+
substitution of Pb
2
+
at
x
=
0
, 0.04, 0.08, 0.12, 0.16 is investigated for the microstructure evolution, ferroelectric (FE) and dielectric properties. It is found that Li
+
and Bi
3
+
substitution can significantly reduce the sintering temperature and simultaneously enhance the dielectric breakdown strength. An ultrahigh energy efficiency (94.0%) and a large energy density (3.22
J/cm
3
)
are achieved in the composition of
x
=
0
.
1
2
with a low sintering temperature (1075∘C).</description><subject>energy efficiency</subject><subject>energy storage</subject><subject>LiBi substitution</subject><subject>PbZrO3-based antiferroelectrics</subject><issn>2010-135X</issn><issn>2010-1368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNplkE1KA0EQhRtRMGgO4G6Wuhit_qn0zFKDP4FAhCgEN0P1n3aYZKRnQvAGXsALehITI9n4Nu_xCj6ox9gZh0vOlbiaCuDAJc6ERAAh1AHrbaucy0FxuM84O2b9tp3DRogFSOyx6XRl2i52qy42y6wJ2aPJ1rF7y87HkX9_fombnV1kcbm5vaSJzA213mW07GLwKTW-9rZL0WbWJ1pE256yo0B16_t_fsKe726fhg_5eHI_Gl6PcycBVW6LoAcChZSeUJsCNRZaoRpogaUg70QoHGrQzmgKZJQFG4wuwaMmKFGesNGO6xqaV-8pLih9VA3F6rdo0mtFqYu29pUMSJwwWCRQXKqy5EaGIHwoEXRhNyzYsdZNql1ro9--F-0e-29j-QPowW9y</recordid><startdate>202402</startdate><enddate>202402</enddate><creator>Liu, Binzhi</creator><creator>Gaur, Anand P. S.</creator><creator>Cui, Jun</creator><creator>Tan, Xiaoli</creator><general>World Scientific Publishing Company</general><general>World Scientific Publishing</general><scope>ADCHV</scope><scope>DOA</scope></search><sort><creationdate>202402</creationdate><title>Substitution of Pb with (Li1∕2Bi1∕2) in PbZrO3-based antiferroelectric ceramics</title><author>Liu, Binzhi ; Gaur, Anand P. S. ; Cui, Jun ; Tan, Xiaoli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-d3054-c8f7625233ea57b857587454672592aed2f8d5707db7afab4c0cfb790e57a0953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>energy efficiency</topic><topic>energy storage</topic><topic>LiBi substitution</topic><topic>PbZrO3-based antiferroelectrics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Binzhi</creatorcontrib><creatorcontrib>Gaur, Anand P. S.</creatorcontrib><creatorcontrib>Cui, Jun</creatorcontrib><creatorcontrib>Tan, Xiaoli</creatorcontrib><collection>World Scientific Open</collection><collection>DOAJ Open Access Journals</collection><jtitle>Journal of advanced dielectrics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Binzhi</au><au>Gaur, Anand P. S.</au><au>Cui, Jun</au><au>Tan, Xiaoli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Substitution of Pb with (Li1∕2Bi1∕2) in PbZrO3-based antiferroelectric ceramics</atitle><jtitle>Journal of advanced dielectrics</jtitle><date>2024-02</date><risdate>2024</risdate><volume>14</volume><issue>1</issue><issn>2010-135X</issn><eissn>2010-1368</eissn><abstract>PbZrO3-based antiferroelectric (AFE) ceramics are promising dielectrics for high-energy-density capacitors due to their reversible phase transitions during charge–discharge cycles. In this work, a new composition series, [Pb
0
.
9
3
−
x
La
0
.
0
2
(Li
1
∕
2
Bi
1
∕
2
)
x
Sr
0
.
0
4
][Zr
0
.
5
7
Sn
0
.
3
4
Ti
0
.
0
9
]O3, with Li
+
and Bi
3
+
substitution of Pb
2
+
at
x
=
0
, 0.04, 0.08, 0.12, 0.16 is investigated for the microstructure evolution, ferroelectric (FE) and dielectric properties. It is found that Li
+
and Bi
3
+
substitution can significantly reduce the sintering temperature and simultaneously enhance the dielectric breakdown strength. An ultrahigh energy efficiency (94.0%) and a large energy density (3.22
J/cm
3
)
are achieved in the composition of
x
=
0
.
1
2
with a low sintering temperature (1075∘C).</abstract><pub>World Scientific Publishing Company</pub><doi>10.1142/S2010135X23500224</doi><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2010-135X |
| ispartof | Journal of advanced dielectrics, 2024-02, Vol.14 (1) |
| issn | 2010-135X 2010-1368 |
| language | eng |
| recordid | cdi_doaj_primary_oai_doaj_org_article_3f5a1a5fc5a04134991b3ff2ef95078c |
| source | World Scientific Journals |
| subjects | energy efficiency energy storage LiBi substitution PbZrO3-based antiferroelectrics |
| title | Substitution of Pb with (Li1∕2Bi1∕2) in PbZrO3-based antiferroelectric ceramics |
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