Characterization and Correction of Evaporative Artifacts in Speleothem Fluid Inclusion Isotope Analyses as Applied to a Stalagmite From Borneo

• Published in: Geochemistry, geophysics, geosystems : G3 geophysics, geosystems : G3, 2023-06, Vol.24 (6), p.n/a
• Main Authors: Fernandez, A., Løland, M. H., Maccali, J., Krüger, Y., Vonhof, H. B., Sodemann, H., Meckler, A. N.
• Format: Article
• Language: English
• Subjects: Calcite; carbonates; Evaporation; fluid inclusions; Fractionation; Hydroclimate; Isotope composition; Isotopes; Low humidity; Meridional overturning circulation; Paleoclimate; Paleotemperatures; Precipitation; Slopes; speleothems; Temperature; Water; water isotopes; Water loss
• ISSN: 1525-2027; 1525-2027
• DOI: 10.1029/2023GC010857

Fluid inclusion water isotope measurements in speleothems have great potential for paleoclimate studies as they enable the reconstruction of precipitation dynamics and land temperatures. Several previous observations, however, suggest that inclusion waters do not always reflect the isotopic composition of surface precipitation. In such cases, dripwaters are thought to be modified by evaporation in the cave environment that results in more positive δ2H and δ18O values and shallow δ2H/δ18O slopes. Although evaporation can occur in cave systems, water can also be lost to evaporation during analysis but before water extraction. Here, we examine the likelihood of this possibility with a stalagmite from Borneo. We demonstrate that many samples lose water, and that water loss is controlled by the type and size of inclusions. With multiple replicate measurements of coeval samples, we calculate an evaporative δ2H/δ18O slope of 1.0 ± 0.6 (2SE). This value is consistent with model predictions of evaporative fractionation at high analytical temperature and low humidity. Finally, we propose a method to correct for this effect. We find that fluid–calcite δ18O paleotemperatures calculated with corrected δ18O data show excellent agreement with recent microthermometry temperature estimates for Borneo, supporting the validity of our approach and implying limited stalagmite δ18O disequilibrium variations. Corrected fluid inclusion δ18O and δ2H values follow the expected hydroclimate response of Borneo to periods of reduced Atlantic Ocean meridional overturning circulation. Our results suggest that careful petrographic examination and multiple replicate measurements are necessary for reliable paleoclimate reconstructions with speleothem fluid inclusion water isotopes. Key Points Fluid inclusions water isotopes in speleothems do not always reflect the composition of precipitation Evaporation during analyses before water extraction affects the accuracy of measurements Artifacts can be corrected to produce reliable paleoclimate reconstructions