Diaqua(1,4,8,11-tetraazacyclotetradecane-κ 4 N 1 , N 4 , N 8 , N 11 )copper(II) didecanoate dihydrate

The CuII atom in the title salt, [Cu(C10H24N4)(H2O)2][CH3(CH2)8CO2]2·2H2O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn–Teller-type tetragonally distorted octahedral geometry. The CuII...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-08, Vol.66 (8), p.m888-m888
Main Authors: Ahmad Tajidi, Nur Syamimi, Abdullah, Norbani, Arifin, Zainudin, Tan, Kong Wai, Ng, Seik Weng
Format: Article
Language:English
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Summary:The CuII atom in the title salt, [Cu(C10H24N4)(H2O)2][CH3(CH2)8CO2]2·2H2O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn–Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N—H...O and O—H...O hydrogen bonds, forming a layer structure parallel to (001).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810025699