The Synthesis of Poly(Vinyl Alcohol) Grafted with Fluorinated Protic Ionic Liquids Containing Sulfo Functional Groups

• Published in: Molecules (Basel, Switzerland) Switzerland), 2021-07, Vol.26 (14), p.4158
• Main Authors: Glińska, Patrycja, Wolan, Andrzej, Kujawski, Wojciech, Rynkowska, Edyta, Kujawa, Joanna
• Format: Article
• Language: English
• Subjects: Acetic acid; Acids; Acylation; Alcohol; chemical modification; Efficiency; Electrolytes; Fluorination; Free radical polymerization; Fuel cells; Fuel technology; Functional groups; Grafting; High temperature; Hydroxyl groups; Imidazole; imidazolium-based ionic liquid; Ionic liquids; Ions; Membranes; poly(vinyl alcohol); Polyethylene; Polymerization; Polymers; Polyvinyl alcohol; protic ionic liquid; Proton exchange membrane fuel cells; Tensile strength
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules26144158

There has been an ongoing need to develop polymer materials with increased performance as proton exchange membranes (PEMs) for middle- and high-temperature fuel cells. Poly(vinyl alcohol) (PVA) is a highly hydrophilic and chemically stable polymer bearing hydroxyl groups, which can be further altered. Protic ionic liquids (proticILs) have been found to be an effective modifying polymer agent used as a proton carrier providing PEMs’ desirable proton conductivity at high temperatures and under anhydrous conditions. In this study, the novel synthesis route of PVA grafted with fluorinated protic ionic liquids bearing sulfo groups (–SO3H) was elaborated. The polymer functionalization with fluorinated proticILs was achieved by the following approaches: (i) the PVA acylation and subsequent reaction with fluorinated sultones and (ii) free-radical polymerization reaction of vinyl acetate derivatives modified with 1-methylimidazole and sultones. These modifications resulted in the PVA being chemically modified with ionic liquids of protic character. The successfully grafted PVA has been characterized using 1H, 19F, and 13C-NMR and FTIR-ATR. The presented synthesis route is a novel approach to PVA functionalization with imidazole-based fluorinated ionic liquids with sulfo groups.