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The fumarate salts of the N -isopropyl- N -methyl derivatives of DMT and psilocin
The solid-state structures of the salts of two substituted tryptamines, namely N -isopropyl- N -methyltryptaminium (MiPT) fumarate {systematic name: [2-(1 H -indol-3-yl)ethyl](methyl)propan-2-ylazanium 3-carboxyprop-2-enoate}, C 14 H 21 N 2 + ·C 4 H 3 O 4 − , and 4-hydroxy- N -isopropyl- N -methyltr...
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Published in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2019-09, Vol.75 (9), p.1316-1320 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The solid-state structures of the salts of two substituted tryptamines, namely
N
-isopropyl-
N
-methyltryptaminium (MiPT) fumarate {systematic name: [2-(1
H
-indol-3-yl)ethyl](methyl)propan-2-ylazanium 3-carboxyprop-2-enoate}, C
14
H
21
N
2
+
·C
4
H
3
O
4
−
, and 4-hydroxy-
N
-isopropyl-
N
-methyltryptaminium (4-HO-MiPT) fumarate monohydrate {systematic name: [2-(4-hydroxy-1
H
-indol-3-yl)ethyl](methyl)propan-2-ylazanium 3-carboxyprop-2-enoate monohydrate}, C
14
H
21
N
2
O
+
·C
4
H
3
O
4
−
·H
2
O, are reported. Both salts possess a protonated tryptammonium cation and a 3-carboxyacrylate (hydrogen fumarate) anion in the asymmetric unit; the 4-HO-MiPT structure also contains a water molecule of crystallization. Both cations feature disorder of the side chain over two orientations, in a 0.630 (3):0.370 (3) ratio for MiPT and a 0.775 (5):0.225 (5) ratio for 4-HO-MiPT. In both extended structures, N—H...O and O—H...O hydrogen bonds generate infinite two-dimensional networks. |
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ISSN: | 2056-9890 2056-9890 |
DOI: | 10.1107/S2056989019011253 |