trans -Dichloridobis[( S )-(−)-1-(4-methylphenyl)ethylamine-κ N ]palladium(II)

The title complex, [PdCl 2 (C 9 H 13 N) 2 ], comprises a single molecule in the asymmetric unit. The Pd II atom is tetracoordinated by two N atoms from two trans -aligned organic ligands and two Cl ligands, forming a square-planar metal coordination environment. The distances from the ortho -H atoms...

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Bibliographic Details
Published in:IUCrData 2024-01, Vol.9 (1), p.x240036, Article x240036
Main Authors: Hernández Téllez, Guadalupe, Moreno Morales, Gloria E., Sharma, Pankaj, Gonzalez, Rodary, Anzaldo, Bertin
Format: Article
Language:English
Subjects:
amine
crystal structure
monodentate ligand
palladium(ii) complex
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Summary:The title complex, [PdCl 2 (C 9 H 13 N) 2 ], comprises a single molecule in the asymmetric unit. The Pd II atom is tetracoordinated by two N atoms from two trans -aligned organic ligands and two Cl ligands, forming a square-planar metal coordination environment. The distances from the ortho -H atoms on the phenyl ring to the central Pd II atom fall within the range 4.70–5.30 Å, precluding any significant intramolecular Pd...H interactions.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314624000361