Mechanisms of stored energy release in silicon carbide materials neutron-irradiated at elevated temperatures

• Published in: Materials & design 2022-02, Vol.214 (NA), p.110413, Article 110413
• Main Authors: Koyanagi, Takaaki, Wang, Hsin, Karakoc, Omer, Katoh, Yutai
• Format: Article
• Language: English
• Subjects: Differential scanning calorimetry; MATERIALS SCIENCE; Neutron irradiation; Silicon carbide; Stored energy release
• ISSN: 0264-1275; 1873-4197
• DOI: 10.1016/j.matdes.2022.110413

[Display omitted] •Stored energy release from irradiated SiC composites did not exceed the specific heat capacity, which is promising for accident tolerant fuel applications.•The model for the energy release behavior derived a total stored energy in irradiated SiC: 425 J/g per 1% swelling.•The mode concludes that recovery of atomistic defects causing irradiation-induced swelling is the source of the stored energy release.•The large energy release of 600 J/g during annealing up to 1,273 K was demonstrated for potential energy storage applications. Understanding the stored energy release behavior of SiC is crucial for the design of SiC-based fuel cladding for light water reactors because stored energy release affects response during accident conditions. Differential scanning calorimetry was used to evaluate the stored energy of monolithic SiC and SiC fiber–reinforced SiC matrix composite variants following neutron irradiation under light water reactor–relevant dose and temperature conditions. The tests were performed at heating rates of 0.5, 3, and 20 K/min up to 1,273 K. The onset temperature of the energy release roughly corresponded to the irradiation temperature, and energy release was delayed as the heating rate increased. The monolithic and composite specimens exhibited similar stored energy release behavior up to ∼ 1,000 K, and above that temperature, the energy release depended more on material type. The energy release measured in this study is below the material-specific heat capacity at temperatures below ∼1,000 K but exceeds it under certain material and annealing conditions at temperatures above ∼1,000 K. The amount of irradiation-induced volumetric swelling of the specimens was an indication of the total stored energy. Based on this observation, the energy release behavior was described by a swelling recovery model.