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Alkyl Silica Hybrid Nanowire Assembly in Improved Superhydrophobic Membranes for RO Filtration
Alkyl silica membranes and wires were synthesized by a sol-gel method, which has the capacity to control the size of the particles or membranes by controlling the reactions. Trimethoxyoctylsilane (C TMOS) was used as a chemical surfactant; poly(vinylpyrrolidone) (PVP) as an emulsifier, dissolved in...
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Published in: | ACS omega 2022-02, Vol.7 (5), p.3940-3948 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Alkyl silica membranes and wires were synthesized by a sol-gel method, which has the capacity to control the size of the particles or membranes by controlling the reactions. Trimethoxyoctylsilane (C
TMOS) was used as a chemical surfactant; poly(vinylpyrrolidone) (PVP) as an emulsifier, dissolved in butanol for emulsion; and tetraethylorthosilicate (TEOS) as a precursor and a source of silica. An assembly of silica wires was fabricated on glass and cotton substrates by the dip-coating technique. Porous membranes and silica wires were observed using scanning electron microscopy (SEM) images. The contact angles of all of the samples were in the range of 140-154° as measured by ImageJ software, which confirmed the hydrophobic nature of the samples. The contact angle was increased by increasing the amount of the surfactant. Phase changes of silica wires and membranes were investigated by thermogravimetric analysis. Chemical bonds of the sample were studied using Fourier transform infrared (FTIR) spectroscopy. The band gap of silica nanowires was measured to be 3.8-3.4 eV using the UV-visible spectrum and decreased as compared to that of bulk silica. These silica-based porous membranes with enhanced transport properties can be used in filtration and separation techniques. This fabricated hybrid silica membrane showed ∼96% salt rejection within a permeation flux of 3.04 L/m
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ISSN: | 2470-1343 2470-1343 |
DOI: | 10.1021/acsomega.1c04498 |