Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials

This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic...

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Bibliographic Details
Published in:Beilstein journal of organic chemistry 2019-02, Vol.15 (1), p.310-332
Main Authors: Żak, Patrycja, Pietraszuk, Cezary
Format: Article
Language:English
Subjects:
Chemistry
Copolymers
Molybdenum
olefin metathesis
Polymerization
Polymers
POSS
Quantum dots
Review
silsesquioxanes
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Summary:This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic diene metathesis (ADMET) copolymerization of divinyl-substituted POSS with α,ω-dienes and ring-opening metathesis polymerization (ROMP) of POSS-substituted norbornene (or other ROMP susceptible cycloolefins) are discussed. Emphasis was put on the synthetic and catalytic aspects rather than on the properties and applications of synthesized materials.
ISSN:1860-5397
2195-951X
1860-5397
DOI:10.3762/bjoc.15.28