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Desulfurization of Fuel by [Bmim]CoCl3 and Potassium Monopersulfate

Functional ionic liquid [Bmim]C°Cl3 was prepared with potassium monopersulfate compound (PMS) to form extraction catalytic oxidative desulfurization system for benzothiophene (BT) removal. The best reaction conditions for removing BT were as follows: m (ionic liquid) = 2 g, m(PMS) = 1.5 g, C (initia...

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Published in:Nature environment and pollution technology 2020-12, Vol.19 (4), p.1749-1753
Main Authors: Zhang, Jun, Xu, Hang, Li, Yang
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Li, Yang
description Functional ionic liquid [Bmim]C°Cl3 was prepared with potassium monopersulfate compound (PMS) to form extraction catalytic oxidative desulfurization system for benzothiophene (BT) removal. The best reaction conditions for removing BT were as follows: m (ionic liquid) = 2 g, m(PMS) = 1.5 g, C (initial sulphur) = 500 ppm, T = 40°C ~ 50°C. The desulfurization rate could be reached at 92.4 %. The ionic liquid still had higher activity after 5 cycles of reuse which exhibited that there was only a slight difference in the amount of the oxidant. It was proved that [Bmim]C°Cl3 ionic liquid combined with oxidant PMS has an excellent desulfurization performance.
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subjects Air pollution
Benzothiophene
Catalytic oxidation
Desulfurization
Desulfurizing
Diesel fuels
environment
Ionic liquids
Ions
Nitrogen dioxide
Outdoor air quality
Oxidants
Oxidizing agents
Pollutants
Potassium
Smog
Sulfur
title Desulfurization of Fuel by [Bmim]CoCl3 and Potassium Monopersulfate
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