Diaquabis(1 H -imidazole-κ N 3 )bis(4-nitrobenzoato-κ O 1 )cadmium

In the centrosymmetric title compound, [Cd(C7H4NO4)2(C3H4N2)2(H2O)2], the CdII atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octahedral geometry. The internal cohesion of the molecule is enhanced by an intramolecular O—H...O hydrogen bond. Inter...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-09, Vol.68 (9), p.m1149-m1149
Main Authors: Mao, Yan-Li, Yu, Xiao-Ke, Lin, Jian-Li
Format: Article
Language:English
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Summary:In the centrosymmetric title compound, [Cd(C7H4NO4)2(C3H4N2)2(H2O)2], the CdII atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octahedral geometry. The internal cohesion of the molecule is enhanced by an intramolecular O—H...O hydrogen bond. Intermolecular O—H...O and C—H...O hydrogen bonds and π–π contacts [centroid–centroid distance = 3.6549 (2) Å] define two-dimensional networks parallel to (001), which are further connected by weaker C—H...O interactions into a weakly connected three-dimensional supramolecular framework.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812033739