Green synthesis of Fe nanoparticles by using Mangifera indica extract and its application in photo-catalytic degradation of dyes

An exceedingly facile green approach that produces a reliable adsorbent based on a transition metal such as Iron (Fe) using Mangifera indica leaf extract at room temperature is described. A single pot method was used for synthesis with no capping agents, surfactants or other templates. The main inte...

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Published in:Water science and technology 2021-04, Vol.83 (7), p.1739-1752
Main Authors: Zulfikar, Mona, Nadeem, Raziya, Javed, Tariq, Jilani, Muhammad Idrees, Javed, Iram
Format: Article
Language:English
Subjects:
Adsorbents
Adsorption
Analytical methods
Biomass
Biomolecules
brilliant green
Catalysis
Chemical synthesis
Chemisorption
Color removal
Coloring Agents
congo red
Degradation
Dosage
Dyes
Efficiency
Electron microscopy
endothermic
Enthalpy
Entropy
fe-nps
Fourier transforms
Free energy
Gibbs free energy
Hydrogen-Ion Concentration
Independent variables
Industrial wastewater
Infrared spectroscopy
Iron
isotherms
Kinetics
Leaves
Mangifera indica
Metals
Nanoparticles
Oxidation
Photodegradation
Plant Extracts
Pollutants
Room temperature
Scanning electron microscopy
Spectroscopy, Fourier Transform Infrared
Statistical methods
Templates
Thermodynamics
Transition metals
Wastewater
Wastewater treatment
Water Pollutants, Chemical
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description An exceedingly facile green approach that produces a reliable adsorbent based on a transition metal such as Iron (Fe) using Mangifera indica leaf extract at room temperature is described. A single pot method was used for synthesis with no capping agents, surfactants or other templates. The main intention of this study is to synthesize iron nanoparticles from leaf extract (Mangifera indica) and examine its degradation potential for photo-catalytic removal of dyes (Congo red and brilliant green) from wastewater. Characterization of synthesized nanoparticles was executed by pH , scanning electron microscopy and Fourier transform infrared spectroscopy studies and results confirm the presence of iron nano-sheets with biomolecules. All photo-catalytic experimental results were assessed by sum of squared estimate of errors and simple linear regression R with dye concentration, pH, contact time and dose rate as dependent and independent variables. Adsorption experimental data was verified by kinetics and isothermal models. Results showed that Langmuir and pseudo second order models give best fitness towards the photo-catalytic adsorption procedure. Thermodynamics revealed that adsorption mechanism is endothermic, described by the values of changes in Gibbs free energy, enthalpy and entropy, and is chemisorption in nature, with spontaneous processes. Overall photo-catalytic adsorption execution with synthesized iron nanoparticles and simple biomass of Mangifera indica gives satisfactory results for treating dye wastewater.
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Overall photo-catalytic adsorption execution with synthesized iron nanoparticles and simple biomass of Mangifera indica gives satisfactory results for treating dye wastewater.</description><identifier>ISSN: 0273-1223</identifier><identifier>EISSN: 1996-9732</identifier><identifier>DOI: 10.2166/wst.2021.074</identifier><identifier>PMID: 33843756</identifier><language>eng</language><publisher>England: IWA Publishing</publisher><subject>Adsorbents ; Adsorption ; Analytical methods ; Biomass ; Biomolecules ; brilliant green ; Catalysis ; Chemical synthesis ; Chemisorption ; Color removal ; Coloring Agents ; congo red ; Degradation ; Dosage ; Dyes ; Efficiency ; Electron microscopy ; endothermic ; Enthalpy ; Entropy ; fe-nps ; Fourier transforms ; Free energy ; Gibbs free energy ; Hydrogen-Ion Concentration ; Independent variables ; Industrial wastewater ; Infrared spectroscopy ; Iron ; isotherms ; Kinetics ; Leaves ; Mangifera indica ; Metals ; Nanoparticles ; Oxidation ; Photodegradation ; Plant Extracts ; Pollutants ; Room temperature ; Scanning electron microscopy ; Spectroscopy, Fourier Transform Infrared ; Statistical methods ; Templates ; Thermodynamics ; Transition metals ; Wastewater ; Wastewater treatment ; Water Pollutants, Chemical</subject><ispartof>Water science and technology, 2021-04, Vol.83 (7), p.1739-1752</ispartof><rights>Copyright IWA Publishing Apr 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c423t-b0d957b07b74fc613188072c677c36bb9acc40144c08ba1730d065cea3f8d4523</citedby><cites>FETCH-LOGICAL-c423t-b0d957b07b74fc613188072c677c36bb9acc40144c08ba1730d065cea3f8d4523</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33843756$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zulfikar, Mona</creatorcontrib><creatorcontrib>Nadeem, Raziya</creatorcontrib><creatorcontrib>Javed, Tariq</creatorcontrib><creatorcontrib>Jilani, Muhammad Idrees</creatorcontrib><creatorcontrib>Javed, Iram</creatorcontrib><title>Green synthesis of Fe nanoparticles by using Mangifera indica extract and its application in photo-catalytic degradation of dyes</title><title>Water science and technology</title><addtitle>Water Sci Technol</addtitle><description>An exceedingly facile green approach that produces a reliable adsorbent based on a transition metal such as Iron (Fe) using Mangifera indica leaf extract at room temperature is described. 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ispartof Water science and technology, 2021-04, Vol.83 (7), p.1739-1752
issn 0273-1223
1996-9732
language eng
recordid cdi_doaj_primary_oai_doaj_org_article_55b116d58c9a4033a945ed82620ac7fa
source Alma/SFX Local Collection
subjects Adsorbents
Adsorption
Analytical methods
Biomass
Biomolecules
brilliant green
Catalysis
Chemical synthesis
Chemisorption
Color removal
Coloring Agents
congo red
Degradation
Dosage
Dyes
Efficiency
Electron microscopy
endothermic
Enthalpy
Entropy
fe-nps
Fourier transforms
Free energy
Gibbs free energy
Hydrogen-Ion Concentration
Independent variables
Industrial wastewater
Infrared spectroscopy
Iron
isotherms
Kinetics
Leaves
Mangifera indica
Metals
Nanoparticles
Oxidation
Photodegradation
Plant Extracts
Pollutants
Room temperature
Scanning electron microscopy
Spectroscopy, Fourier Transform Infrared
Statistical methods
Templates
Thermodynamics
Transition metals
Wastewater
Wastewater treatment
Water Pollutants, Chemical
title Green synthesis of Fe nanoparticles by using Mangifera indica extract and its application in photo-catalytic degradation of dyes
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