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Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates

An improved synthesis of 1- -acyl glucosyl esters that avoids the use of expensive Ag reagents as well as the hydrolysis of unstable glucosyl bromides is reported. Notably, β-configuration products were obtained exclusively in good yields.

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Published in:Molecules (Basel, Switzerland) Switzerland), 2017-04, Vol.22 (4), p.662
Main Authors: Chen, Yu, Lu, Huan, Chen, Yanyu, Yu, Wansheng, Dai, Hui, Pan, Xianhua
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Language:English
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cited_by cdi_FETCH-LOGICAL-c493t-379256b9dd0463ccc0cc61287ee358f8524f895974ca3ca2fcabb095d11029523
cites cdi_FETCH-LOGICAL-c493t-379256b9dd0463ccc0cc61287ee358f8524f895974ca3ca2fcabb095d11029523
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container_issue 4
container_start_page 662
container_title Molecules (Basel, Switzerland)
container_volume 22
creator Chen, Yu
Lu, Huan
Chen, Yanyu
Yu, Wansheng
Dai, Hui
Pan, Xianhua
description An improved synthesis of 1- -acyl glucosyl esters that avoids the use of expensive Ag reagents as well as the hydrolysis of unstable glucosyl bromides is reported. Notably, β-configuration products were obtained exclusively in good yields.
doi_str_mv 10.3390/molecules22040662
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subjects Acetates - chemical synthesis
Acetates - chemistry
aliphatic acids
aromatic acids
Brand names
Cosmetics
Esters - chemical synthesis
Fatty acids
Fluorides
Glucosides - chemical synthesis
Glucosides - chemistry
glucosyl bromide
glucosyl esters
Hydrolysis
Magnetic Resonance Spectroscopy
Medical supplies
Reagents
Structure-Activity Relationship
title Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates
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