Mesoporous Silica Modified with 2-Phenylimidazo[1,2-a] pyridine-3-carbaldehyde as an Effective Adsorbent for Cu(II) from Aqueous Solutions: A Combined Experimental and Theoretical Study

• Published in: Molecules (Basel, Switzerland) Switzerland), 2022-08, Vol.27 (16), p.5168
• Main Authors: Saddik, Rafik, Hammoudan, Imad, Tighadouini, Said, Roby, Othmane, Radi, Smaail, Al-Zaben, Maha I, Ben Bacha, Abir, Masand, Vijay H, Almarhoon, Zainab M
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Aqueous solutions; Comparative analysis; Copper; heavy metals; Hydrogen-Ion Concentration; Kinetics; Ligands; Models, Theoretical; Nitrogen; NMR; Nuclear magnetic resonance; Pyridine; Pyridines; Selectivity; Silica; silica functionalization; Silicon Dioxide - chemistry; Solutions; Spectroscopy, Fourier Transform Infrared; Water - chemistry; Water Pollutants, Chemical - chemistry; Water pollution
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules27165168

In this study, we will present an efficient and selective adsorbent for the removal of Cu(II) ions from aqueous solutions. The silica-based adsorbent is functionalized by 2-phenylimidazo[1,2-a] pyridine-3-carbaldehyde (SiN-imd-py) and the characterization was carried out by applying various techniques including FT-IR, SEM, TGA and elemental analysis. The SiN-imd-py adsorbent shows a good selectivity and high adsorption capacity towards Cu(II) and reached 100 mg/g at pH = 6 and T = 25 °C. This adsorption capacity is important compared to other similar adsorbents which are currently published. The adsorption mechanism, thermodynamics, reusability and the effect of different experimental conditions, such as contact time, pH and temperature, on the adsorption process, were also investigated. In addition, a theoretical study was carried out to understand the adsorption mechanism and the active sites of the adsorbent, as well as the stability of the complex formed and the nature of the bonds.