Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis

Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1 bis(boryl)alkanes and alkenes to provide informatio...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2020-02, Vol.25 (4), p.959
Main Authors: Babu, K Naresh, Massarwe, Fedaa, Reddy, Rajasekhar, Eghbarieh, Nadim, Jakob, Manuella, Masarwa, Ahmad
Format: Article
Language:English
Subjects:
1,1-bis(boryl)alkanes and alkenes
bismetallated organic compounds
chemoselective transformations
Review
suzuki–miyaura cross-coupling
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Summary:Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1 bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules25040959