Use of the SSF equations in the Kojima-Moon-Ochi thermodynamic consistency test of isothermal vapour-liquid equilibrium data

The Kojima-Moon-Ochi (KMO) thermodynamic consistency test of vapour-liquid equilibrium (VLE) measurements for 32 isothermal data sets of binary systems of various complexity was applied using two fitting equations: the Redlich-Kister equation and the Sum of Symmetrical Functions. It was shown that t...

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Published in:Journal of the Serbian Chemical Society 2000, Vol.65 (12), p.877-889
Main Authors: Jelic, Jelena, Tasic, Aleksandar, Djordjevic, Bojan, Serbanovic, Slobodan
Format: Article
Language:English
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binary system
thermodynamic consistency test
vapour-liquid equilibria
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container_issue 12
container_start_page 877
container_title Journal of the Serbian Chemical Society
container_volume 65
creator Jelic, Jelena
Tasic, Aleksandar
Djordjevic, Bojan
Serbanovic, Slobodan
description The Kojima-Moon-Ochi (KMO) thermodynamic consistency test of vapour-liquid equilibrium (VLE) measurements for 32 isothermal data sets of binary systems of various complexity was applied using two fitting equations: the Redlich-Kister equation and the Sum of Symmetrical Functions. It was shown that the enhanced reliability of the fitting of the experimental data can change the conclusions drawn on their thermodynamic consistency in those cases of VLE data sets that are estimated to be near the border of consistency. nema
doi_str_mv 10.2298/JSC0012877J
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subjects binary system
thermodynamic consistency test
vapour-liquid equilibria
title Use of the SSF equations in the Kojima-Moon-Ochi thermodynamic consistency test of isothermal vapour-liquid equilibrium data
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