Global upper-tropospheric formaldehyde: seasonal cycles observed by the ACE-FTS satellite instrument

• Published in: Atmospheric chemistry and physics 2009-01, Vol.9 (12), p.3893-3910
• Main Authors: Dufour, G., Szopa, S., Barkley, M. P., Boone, C. D., Perrin, A., Palmer, P. I., Bernath, P. F.
• Format: Article
• Language: English
• Subjects: Continental interfaces, environment; Ocean, Atmosphere; Sciences of the Universe
• ISSN: 1680-7324; 1680-7316; 1680-7324
• DOI: 10.5194/acp-9-3893-2009

Seasonally-resolved upper tropospheric profiles of formaldehyde (HCHO) observed by the ACE Fourier transform spectrometer (ACE-FTS) on a near-global scale are presented for the time period from March 2004 to November 2006. Large upper tropospheric HCHO mixing ratios (>150 pptv) are observed during the growing season of the terrestrial biosphere in the Northern Hemisphere and during the biomass burning season in the Southern Hemisphere. The total errors estimated for the retrieved mixing ratios range from 30 to 40% in the upper troposphere and increase in the lower stratosphere. The sampled HCHO concentrations are in satisfactory agreement with previous aircraft and satellite observations with a negative bias (0.9). Both models underestimate the summer maximum over Europe and Russia and differences in the emissions used for North America result in a good reproduction of the summer maximum by GEOS-Chem but in an underestimate by LMDz-INCA. Globally, GEOS-Chem reproduces well the observations on average over one year but has some difficulties in reproducing the spatial variability of the observations. LMDz-INCA shows significant bias in the Southern Hemisphere, perhaps related to an underestimation of methane, but better reproduces the temporal and spatial variations. The differences between the models underline the large uncertainties that remain in the emissions of HCHO precursors.