Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes

A mild, visible-light-induced, regioselective cascade sulfonylation-cyclization of 1,5-dienes with sulfonyl chlorides through the intermolecular radical addition/cyclization of alkenes C(sp )-H was developed. This procedure proceeds well and affords a mild and efficient route to a range of monosulfo...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2023-07, Vol.28 (14), p.5473
Main Authors: Ding, Ran, Li, Liang, Yu, Ya-Ting, Zhang, Bing, Wang, Pei-Long
Format: Article
Language:English
Subjects:
Carbon
Chloride
cyclization
dienes
Hydrocarbons
Light emitting diodes
Natural products
Oxidation
pyrrolin-2-ones
radical
regioselective
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Summary:A mild, visible-light-induced, regioselective cascade sulfonylation-cyclization of 1,5-dienes with sulfonyl chlorides through the intermolecular radical addition/cyclization of alkenes C(sp )-H was developed. This procedure proceeds well and affords a mild and efficient route to a range of monosulfonylated pyrrolin-2-ones at room temperatures.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules28145473