Modifications of EHPDB Physical Properties through Doping with Fe2O3 Nanoparticles (Part II)

• Published in: International journal of molecular sciences 2022-01, Vol.23 (1), p.50
• Main Authors: Lalik, Sebastian, Stefańczyk, Olaf, Górska, Natalia, Kumar, Kunal, Ohkoshi, Shin-ichi, Marzec, Monika
• Format: Article
• Language: English
• Subjects: Absorption spectra; Admixtures; Dielectric constant; dielectric relaxation; Dielectric strength; Ferric oxide; ferroelectric liquid crystal; Ferroelectric materials; Hysteresis; Hysteresis loops; Light; light absorption; Liquid crystals; Magnetic measurement; magnetization; metal-organic nanocomposite; Molecular dynamics; Molecular structure; Nanocomposites; Nanomaterials; Nanoparticles; Organic chemicals; Phase transitions; Physical properties; Polymers; Quantum dots; Spectroscopy; Superconducting quantum interference devices; Vibrations; Viscosity; γ-Fe2O3 nanoparticles
• ISSN: 1422-0067; 1661-6596; 1422-0067
• DOI: 10.3390/ijms23010050

The aim of our study was to analyze the influence of various concentrations of γ-Fe2O3 nanoparticles on the physical properties of the liquid crystalline ferroelectric SmC* phase, as well as to check the effect of introducing nanoparticles in the LC matrix on their properties in the prepared five nanocomposites. UV-vis spectroscopy showed that the admixture reduced the absorption of nanocomposites in the UV range, additional absorption bands appeared, and all nanocomposites were transparent in the range of 500–850 nm. The molecular dynamics in particular phases of the nanocomposites were investigated by the dielectric spectroscopy method, and it was found that nanoparticles caused a significant increase in the dielectric constant at low frequencies, a strong modification of the dielectric processes in the SmC* phase, and the emergence of new relaxation processes for the highest dopant concentrations. SQUID magnetometry allowed us to determine the magnetic nature of the nanoparticles used, and to show that the blocked state of nanoparticles was preserved in nanocomposites (hysteresis loops were also registered in the ferroelectric SmC* phase). The dependence of the coercive field on the admixture concentration and the widening of the hysteresis loop in nanocomposites in relation to pure nanoparticles were also found. In turn, the FT-MIR spectroscopy method was used to check the influence of the impurity concentration on the formation/disappearance or modification of the absorption bands, and the modification of both the FWHM and the maximum positions for the four selected vibrations in the MIR range, as well as the discontinuous behavior of these parameters at the phase transitions, were found.