Loading…
Ultraconformal Horizontal Zinc Deposition toward Dendrite‐Free Anode
Aqueous zinc (Zn)‐ion batteries (ZIBs) have been considered as the most promising candidate for large‐scale energy storage system. However, the severe and uncontrollable dendrite growth of Zn anodes hinders the practical application. Herein, an ultraconformal horizontal Zn deposition is achieved, wh...
Saved in:
Published in: | Small structures 2023-01, Vol.4 (1), p.n/a |
---|---|
Main Authors: | , , , , , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c4234-664294b410e2c3719714c73a5772df35147ac98d07b4f93dbf8d6d614a80ec2f3 |
---|---|
cites | cdi_FETCH-LOGICAL-c4234-664294b410e2c3719714c73a5772df35147ac98d07b4f93dbf8d6d614a80ec2f3 |
container_end_page | n/a |
container_issue | 1 |
container_start_page | |
container_title | Small structures |
container_volume | 4 |
creator | Zou, Juan Zeng, Ziyue Wang, Chenyang Zhu, Xiaohui Zhang, Jiaqian Lan, Haihui Li, Linyang Yu, Yantao Wang, Huiliu Zhu, Xiaolong Zhang, Yile Zeng, Mengqi Fu, Lei |
description | Aqueous zinc (Zn)‐ion batteries (ZIBs) have been considered as the most promising candidate for large‐scale energy storage system. However, the severe and uncontrollable dendrite growth of Zn anodes hinders the practical application. Herein, an ultraconformal horizontal Zn deposition is achieved, which is profiting from the epitaxial interface (InGaZn6O9) formed via spontaneously alloying between liquid Ga–In alloy (EGaIn) and Zn. The exposed (0016) plane of InGaZn6O9 matches well with (002) plane of Zn, inducing horizontal and dense Zn deposition. The resultant anode endows with prolonged cycling stability, and the full battery paired with MnO2 exhibits a stable lifespan over 4400 cycles at 5 A g−1. Meanwhile, the self‐formed ultraconformal interface realizes 360° no dead angle protection of anode, which is promising in flexible electronics. And there is no obvious capacity recession of the pouch cell even after bending 180°, demonstrating impressive flexibility. More importantly, the interface can be simply fabricated over a large area, displaying the large‐scale viability. The tailored approach delivers a constructive guideline for dendrite‐free Zn anode, showing great potential in the industrial production.
Herein, an effective strategy is reported to accomplish ultraconformal horizontal Zn deposition via spontaneous formation of epitaxial interface. It can achieve 360° no dead angle protection to suppress the growth of Zn dendrites. The resulted anode exhibits excellent long‐term cycling stability and the corresponding full battery shows outstanding flexibility. The simple approach makes the large‐scale application feasible. |
doi_str_mv | 10.1002/sstr.202200194 |
format | article |
fullrecord | <record><control><sourceid>proquest_doaj_</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_5db117edbcde426a92fff69c6f718744</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_5db117edbcde426a92fff69c6f718744</doaj_id><sourcerecordid>2762486278</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4234-664294b410e2c3719714c73a5772df35147ac98d07b4f93dbf8d6d614a80ec2f3</originalsourceid><addsrcrecordid>eNqFUE1LAzEUXETBUnv1vOB5a5LNJptjqdYWCoJtL15CNh-Sst3UZEupJ3-Cv9FfYupK9ebpDcPMvPcmSa4hGEIA0G0IrR8igBAAkOGzpIdIWWYYEHT-B18mgxDWIBoKCCmjvWSyqlsvpGuM8xtRp1Pn7Ztr2gifbSPTO711wbbWNWnr9sKryDTK21Z_vn9MvNbpqHFKXyUXRtRBD35mP1lN7pfjaTZ_fJiNR_NMYpTjjBCMGK4wBBrJnEJGIZY0FwWlSJm8gJgKyUoFaIUNy1VlSkUUgViUQEtk8n4y63KVE2u-9XYj_IE7Yfk34fwLF761sta8UFX8UatKKo0REQwZYwiTxFBYUoxj1k2XtfXudadDy9du55t4PkeUIFwSRMuoGnYq6V0IXpvTVgj4sXp-rJ6fqo8G1hn2ttaHf9R8sVg-_Xq_ALYfiEw</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2762486278</pqid></control><display><type>article</type><title>Ultraconformal Horizontal Zinc Deposition toward Dendrite‐Free Anode</title><source>Wiley_OA刊</source><creator>Zou, Juan ; Zeng, Ziyue ; Wang, Chenyang ; Zhu, Xiaohui ; Zhang, Jiaqian ; Lan, Haihui ; Li, Linyang ; Yu, Yantao ; Wang, Huiliu ; Zhu, Xiaolong ; Zhang, Yile ; Zeng, Mengqi ; Fu, Lei</creator><creatorcontrib>Zou, Juan ; Zeng, Ziyue ; Wang, Chenyang ; Zhu, Xiaohui ; Zhang, Jiaqian ; Lan, Haihui ; Li, Linyang ; Yu, Yantao ; Wang, Huiliu ; Zhu, Xiaolong ; Zhang, Yile ; Zeng, Mengqi ; Fu, Lei</creatorcontrib><description>Aqueous zinc (Zn)‐ion batteries (ZIBs) have been considered as the most promising candidate for large‐scale energy storage system. However, the severe and uncontrollable dendrite growth of Zn anodes hinders the practical application. Herein, an ultraconformal horizontal Zn deposition is achieved, which is profiting from the epitaxial interface (InGaZn6O9) formed via spontaneously alloying between liquid Ga–In alloy (EGaIn) and Zn. The exposed (0016) plane of InGaZn6O9 matches well with (002) plane of Zn, inducing horizontal and dense Zn deposition. The resultant anode endows with prolonged cycling stability, and the full battery paired with MnO2 exhibits a stable lifespan over 4400 cycles at 5 A g−1. Meanwhile, the self‐formed ultraconformal interface realizes 360° no dead angle protection of anode, which is promising in flexible electronics. And there is no obvious capacity recession of the pouch cell even after bending 180°, demonstrating impressive flexibility. More importantly, the interface can be simply fabricated over a large area, displaying the large‐scale viability. The tailored approach delivers a constructive guideline for dendrite‐free Zn anode, showing great potential in the industrial production.
Herein, an effective strategy is reported to accomplish ultraconformal horizontal Zn deposition via spontaneous formation of epitaxial interface. It can achieve 360° no dead angle protection to suppress the growth of Zn dendrites. The resulted anode exhibits excellent long‐term cycling stability and the corresponding full battery shows outstanding flexibility. The simple approach makes the large‐scale application feasible.</description><identifier>ISSN: 2688-4062</identifier><identifier>EISSN: 2688-4062</identifier><identifier>DOI: 10.1002/sstr.202200194</identifier><language>eng</language><publisher>Weinheim: John Wiley & Sons, Inc</publisher><subject>Adsorption ; Anodes ; Anodic protection ; aqueous zinc-ion batteries ; dendrite-free anodes ; Dendritic structure ; Deposition ; Electrodes ; Energy storage ; Flexible components ; Gallium base alloys ; horizontal zinc depositions ; Manganese dioxide ; Morphology ; Plating ; ultraconformal ; Zinc</subject><ispartof>Small structures, 2023-01, Vol.4 (1), p.n/a</ispartof><rights>2022 The Authors. Small Structures published by Wiley‐VCH GmbH</rights><rights>Copyright John Wiley & Sons, Inc. 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4234-664294b410e2c3719714c73a5772df35147ac98d07b4f93dbf8d6d614a80ec2f3</citedby><cites>FETCH-LOGICAL-c4234-664294b410e2c3719714c73a5772df35147ac98d07b4f93dbf8d6d614a80ec2f3</cites><orcidid>0000-0003-1356-4422</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fsstr.202200194$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fsstr.202200194$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,11562,27924,27925,46052,46476</link.rule.ids></links><search><creatorcontrib>Zou, Juan</creatorcontrib><creatorcontrib>Zeng, Ziyue</creatorcontrib><creatorcontrib>Wang, Chenyang</creatorcontrib><creatorcontrib>Zhu, Xiaohui</creatorcontrib><creatorcontrib>Zhang, Jiaqian</creatorcontrib><creatorcontrib>Lan, Haihui</creatorcontrib><creatorcontrib>Li, Linyang</creatorcontrib><creatorcontrib>Yu, Yantao</creatorcontrib><creatorcontrib>Wang, Huiliu</creatorcontrib><creatorcontrib>Zhu, Xiaolong</creatorcontrib><creatorcontrib>Zhang, Yile</creatorcontrib><creatorcontrib>Zeng, Mengqi</creatorcontrib><creatorcontrib>Fu, Lei</creatorcontrib><title>Ultraconformal Horizontal Zinc Deposition toward Dendrite‐Free Anode</title><title>Small structures</title><description>Aqueous zinc (Zn)‐ion batteries (ZIBs) have been considered as the most promising candidate for large‐scale energy storage system. However, the severe and uncontrollable dendrite growth of Zn anodes hinders the practical application. Herein, an ultraconformal horizontal Zn deposition is achieved, which is profiting from the epitaxial interface (InGaZn6O9) formed via spontaneously alloying between liquid Ga–In alloy (EGaIn) and Zn. The exposed (0016) plane of InGaZn6O9 matches well with (002) plane of Zn, inducing horizontal and dense Zn deposition. The resultant anode endows with prolonged cycling stability, and the full battery paired with MnO2 exhibits a stable lifespan over 4400 cycles at 5 A g−1. Meanwhile, the self‐formed ultraconformal interface realizes 360° no dead angle protection of anode, which is promising in flexible electronics. And there is no obvious capacity recession of the pouch cell even after bending 180°, demonstrating impressive flexibility. More importantly, the interface can be simply fabricated over a large area, displaying the large‐scale viability. The tailored approach delivers a constructive guideline for dendrite‐free Zn anode, showing great potential in the industrial production.
Herein, an effective strategy is reported to accomplish ultraconformal horizontal Zn deposition via spontaneous formation of epitaxial interface. It can achieve 360° no dead angle protection to suppress the growth of Zn dendrites. The resulted anode exhibits excellent long‐term cycling stability and the corresponding full battery shows outstanding flexibility. The simple approach makes the large‐scale application feasible.</description><subject>Adsorption</subject><subject>Anodes</subject><subject>Anodic protection</subject><subject>aqueous zinc-ion batteries</subject><subject>dendrite-free anodes</subject><subject>Dendritic structure</subject><subject>Deposition</subject><subject>Electrodes</subject><subject>Energy storage</subject><subject>Flexible components</subject><subject>Gallium base alloys</subject><subject>horizontal zinc depositions</subject><subject>Manganese dioxide</subject><subject>Morphology</subject><subject>Plating</subject><subject>ultraconformal</subject><subject>Zinc</subject><issn>2688-4062</issn><issn>2688-4062</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>DOA</sourceid><recordid>eNqFUE1LAzEUXETBUnv1vOB5a5LNJptjqdYWCoJtL15CNh-Sst3UZEupJ3-Cv9FfYupK9ebpDcPMvPcmSa4hGEIA0G0IrR8igBAAkOGzpIdIWWYYEHT-B18mgxDWIBoKCCmjvWSyqlsvpGuM8xtRp1Pn7Ztr2gifbSPTO711wbbWNWnr9sKryDTK21Z_vn9MvNbpqHFKXyUXRtRBD35mP1lN7pfjaTZ_fJiNR_NMYpTjjBCMGK4wBBrJnEJGIZY0FwWlSJm8gJgKyUoFaIUNy1VlSkUUgViUQEtk8n4y63KVE2u-9XYj_IE7Yfk34fwLF761sta8UFX8UatKKo0REQwZYwiTxFBYUoxj1k2XtfXudadDy9du55t4PkeUIFwSRMuoGnYq6V0IXpvTVgj4sXp-rJ6fqo8G1hn2ttaHf9R8sVg-_Xq_ALYfiEw</recordid><startdate>202301</startdate><enddate>202301</enddate><creator>Zou, Juan</creator><creator>Zeng, Ziyue</creator><creator>Wang, Chenyang</creator><creator>Zhu, Xiaohui</creator><creator>Zhang, Jiaqian</creator><creator>Lan, Haihui</creator><creator>Li, Linyang</creator><creator>Yu, Yantao</creator><creator>Wang, Huiliu</creator><creator>Zhu, Xiaolong</creator><creator>Zhang, Yile</creator><creator>Zeng, Mengqi</creator><creator>Fu, Lei</creator><general>John Wiley & Sons, Inc</general><general>Wiley-VCH</general><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0003-1356-4422</orcidid></search><sort><creationdate>202301</creationdate><title>Ultraconformal Horizontal Zinc Deposition toward Dendrite‐Free Anode</title><author>Zou, Juan ; Zeng, Ziyue ; Wang, Chenyang ; Zhu, Xiaohui ; Zhang, Jiaqian ; Lan, Haihui ; Li, Linyang ; Yu, Yantao ; Wang, Huiliu ; Zhu, Xiaolong ; Zhang, Yile ; Zeng, Mengqi ; Fu, Lei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4234-664294b410e2c3719714c73a5772df35147ac98d07b4f93dbf8d6d614a80ec2f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Adsorption</topic><topic>Anodes</topic><topic>Anodic protection</topic><topic>aqueous zinc-ion batteries</topic><topic>dendrite-free anodes</topic><topic>Dendritic structure</topic><topic>Deposition</topic><topic>Electrodes</topic><topic>Energy storage</topic><topic>Flexible components</topic><topic>Gallium base alloys</topic><topic>horizontal zinc depositions</topic><topic>Manganese dioxide</topic><topic>Morphology</topic><topic>Plating</topic><topic>ultraconformal</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zou, Juan</creatorcontrib><creatorcontrib>Zeng, Ziyue</creatorcontrib><creatorcontrib>Wang, Chenyang</creatorcontrib><creatorcontrib>Zhu, Xiaohui</creatorcontrib><creatorcontrib>Zhang, Jiaqian</creatorcontrib><creatorcontrib>Lan, Haihui</creatorcontrib><creatorcontrib>Li, Linyang</creatorcontrib><creatorcontrib>Yu, Yantao</creatorcontrib><creatorcontrib>Wang, Huiliu</creatorcontrib><creatorcontrib>Zhu, Xiaolong</creatorcontrib><creatorcontrib>Zhang, Yile</creatorcontrib><creatorcontrib>Zeng, Mengqi</creatorcontrib><creatorcontrib>Fu, Lei</creatorcontrib><collection>Wiley_OA刊</collection><collection>Wiley Free Archive</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Small structures</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zou, Juan</au><au>Zeng, Ziyue</au><au>Wang, Chenyang</au><au>Zhu, Xiaohui</au><au>Zhang, Jiaqian</au><au>Lan, Haihui</au><au>Li, Linyang</au><au>Yu, Yantao</au><au>Wang, Huiliu</au><au>Zhu, Xiaolong</au><au>Zhang, Yile</au><au>Zeng, Mengqi</au><au>Fu, Lei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultraconformal Horizontal Zinc Deposition toward Dendrite‐Free Anode</atitle><jtitle>Small structures</jtitle><date>2023-01</date><risdate>2023</risdate><volume>4</volume><issue>1</issue><epage>n/a</epage><issn>2688-4062</issn><eissn>2688-4062</eissn><abstract>Aqueous zinc (Zn)‐ion batteries (ZIBs) have been considered as the most promising candidate for large‐scale energy storage system. However, the severe and uncontrollable dendrite growth of Zn anodes hinders the practical application. Herein, an ultraconformal horizontal Zn deposition is achieved, which is profiting from the epitaxial interface (InGaZn6O9) formed via spontaneously alloying between liquid Ga–In alloy (EGaIn) and Zn. The exposed (0016) plane of InGaZn6O9 matches well with (002) plane of Zn, inducing horizontal and dense Zn deposition. The resultant anode endows with prolonged cycling stability, and the full battery paired with MnO2 exhibits a stable lifespan over 4400 cycles at 5 A g−1. Meanwhile, the self‐formed ultraconformal interface realizes 360° no dead angle protection of anode, which is promising in flexible electronics. And there is no obvious capacity recession of the pouch cell even after bending 180°, demonstrating impressive flexibility. More importantly, the interface can be simply fabricated over a large area, displaying the large‐scale viability. The tailored approach delivers a constructive guideline for dendrite‐free Zn anode, showing great potential in the industrial production.
Herein, an effective strategy is reported to accomplish ultraconformal horizontal Zn deposition via spontaneous formation of epitaxial interface. It can achieve 360° no dead angle protection to suppress the growth of Zn dendrites. The resulted anode exhibits excellent long‐term cycling stability and the corresponding full battery shows outstanding flexibility. The simple approach makes the large‐scale application feasible.</abstract><cop>Weinheim</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/sstr.202200194</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-1356-4422</orcidid><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 2688-4062 |
ispartof | Small structures, 2023-01, Vol.4 (1), p.n/a |
issn | 2688-4062 2688-4062 |
language | eng |
recordid | cdi_doaj_primary_oai_doaj_org_article_5db117edbcde426a92fff69c6f718744 |
source | Wiley_OA刊 |
subjects | Adsorption Anodes Anodic protection aqueous zinc-ion batteries dendrite-free anodes Dendritic structure Deposition Electrodes Energy storage Flexible components Gallium base alloys horizontal zinc depositions Manganese dioxide Morphology Plating ultraconformal Zinc |
title | Ultraconformal Horizontal Zinc Deposition toward Dendrite‐Free Anode |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T08%3A09%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_doaj_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ultraconformal%20Horizontal%20Zinc%20Deposition%20toward%20Dendrite%E2%80%90Free%20Anode&rft.jtitle=Small%20structures&rft.au=Zou,%20Juan&rft.date=2023-01&rft.volume=4&rft.issue=1&rft.epage=n/a&rft.issn=2688-4062&rft.eissn=2688-4062&rft_id=info:doi/10.1002/sstr.202200194&rft_dat=%3Cproquest_doaj_%3E2762486278%3C/proquest_doaj_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c4234-664294b410e2c3719714c73a5772df35147ac98d07b4f93dbf8d6d614a80ec2f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2762486278&rft_id=info:pmid/&rfr_iscdi=true |