A Comparison of the Sensing Behavior for Pt-Mo/C-, Pt-Zr/C-, Pt-Fe-Ir/C-, and Pt/C-Modified Glassy Carbon Electrodes for the Oxidation of Ascorbic Acid and Dopamine

• Published in: Catalysts 2023-02, Vol.13 (2), p.337
• Main Authors: Weng, Yu-Ching, Su-Chen, Jia-Yi, Yang, Ting-Yu, Chiang, Chieh-Lin
• Format: Article
• Language: English
• Subjects: Acids; Analysis; Ascorbic acid; Carbon black; Cardiac glycosides; Cardiotonic agents; Catalysts; Chemical reactions; Chemical reduction; Citric acid; Diffusion coefficient; Diffusion rate; Dopamine; Electric properties; Electrical measurement; Electrocatalysts; Electrodes; Glassy carbon; Graphene; Iridium; Iron; Metals; Molybdenum; Nanoparticles; Oxidation; Particle size; Phenols; Platinum; Pt-Fe-Ir/C; Pt-Mo/C; Pt-Zr/C; Pt/C; Sensitivity; Sensors; Tartaric acid; Uric acid; Vitamin C; Voltammetry; Zirconium
• ISSN: 2073-4344; 2073-4344
• DOI: 10.3390/catal13020337

This study compares the sensing performance for platinum-molybdenum-, platinum-zirconium-, platinum-iron-iridium-, and platinum-modified electrodes in terms of the amperometric detection of ascorbic acid (AA) and dopamine (DA). The Pt, Pt-Mo, Pt-Zr, and Pt-Fe-Ir electrocatalysts are fabricated by chemical reduction on a carbon black support (XC-72) and are further modified on a glassy carbon electrode (GCE) as sensing electrodes. The Pt-Mo/C/GCE exhibits better electrocatalytic activity toward AA and DA than the Pt/C/GCE, Pt-Zr/C/GCE, and Pt-Fe-Ir/C/GCE. The Pt-Mo/C/GCE exhibits a sensitivity of 31.29 µA mM−1 to AA at 0.3 V vs. Ag/AgCl and a sensitivity of 72.24 µA mM−1 to DA at 0.6 V vs. Ag/AgCl and is reproducible and stable. This electrode has a respective limit of detection of 7.69 and 6.14 µM for AA and DA. Sucrose, citric acid, tartaric acid, and uric acid do not interfere with AA and DA detection. The diffusion coefficient and kinetic parameters, such as the catalytic rate constant and the heterogeneous rate constant for AA and DA, are determined using electrochemical approaches.