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Naphthalocyanine-Based NIR Organic Photodiode: Understanding the Role of Different Types of Fullerenes

In this work, we presented experimental observation on solution-processed bulk heterojunction organic photodiode using vanadyl 2,11,20,29-tetra tert-butyl 2,3 naphthalocyanine (VTTBNc) as a p-type material. VTTBNc is blended with two different acceptors, which are PC61BM and PC71BM, to offer further...

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Published in:Micromachines (Basel) 2021-11, Vol.12 (11), p.1383
Main Authors: Alwi, Siti Anis Khairani, Hisamuddin, Syaza Nafisah, Abdullah, Shahino Mah, Anuar, Afiq, Abdul Rahim, Atiqah Husna, Majid, Siti Rohana, Bawazeer, Tahani M., Alsoufi, Mohammad S., Alsenany, Nourah, Supangat, Azzuliani
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container_issue 11
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container_title Micromachines (Basel)
container_volume 12
creator Alwi, Siti Anis Khairani
Hisamuddin, Syaza Nafisah
Abdullah, Shahino Mah
Anuar, Afiq
Abdul Rahim, Atiqah Husna
Majid, Siti Rohana
Bawazeer, Tahani M.
Alsoufi, Mohammad S.
Alsenany, Nourah
Supangat, Azzuliani
description In this work, we presented experimental observation on solution-processed bulk heterojunction organic photodiode using vanadyl 2,11,20,29-tetra tert-butyl 2,3 naphthalocyanine (VTTBNc) as a p-type material. VTTBNc is blended with two different acceptors, which are PC61BM and PC71BM, to offer further understanding in evaluating the performance in organic photodiode (OPD). The blend film of VTTBNc:PC71BM with a volumetric ratio of 1:1 exhibits optimized performance in the VTTBNc blend structure with 2.31 × 109 Jones detectivity and 26.11 mA/W responsivity at a −1 V bias. The response and recovery time of VTTBNc:PC71BM were recorded as 241 ms and 310 ms, respectively. The light absorption measurement demonstrated that VTTBNc could extend the light absorption to the near-infrared (NIR) region. The detail of the enhancement of the performance by adding VTTBNc to the blend was further explained in the discussion section.
doi_str_mv 10.3390/mi12111383
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subjects Electrodes
Electromagnetic absorption
fullerene
Fullerenes
Glass substrates
Heterojunctions
Light
naphthalocyanine
Near infrared radiation
NIR
organic photodiode
Performance evaluation
Photodiodes
Recovery time
solution-processed
Spectrum analysis
title Naphthalocyanine-Based NIR Organic Photodiode: Understanding the Role of Different Types of Fullerenes
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