Selective Recognition and Reversible “Turn-Off” Fluorescence Sensing of Acetate (CH3COO−) Anion at Ppb Level Using a Simple Quinizarin Fluorescent Dye

• Published in: Chemistry an international journal 2022-10, Vol.4 (4), p.1407-1416
• Main Authors: Noushija, Mannanthara Kunhumon, Shanmughan, Ananthu, Mohan, Binduja, Shanmugaraju, Sankarasekaran
• Format: Article
• Language: English
• Subjects: Absorption spectra; acetate anion sensing; Anions; Binding; chemosensor; Colorimetry; Dyes; Emission analysis; Emission spectra; Fluorescence; Fluorescent dyes; fluorescent sensors for anions; Hydrogen; Nitrogen dioxide; Organic chemicals; Pollution monitoring; quinizarin dye; Sensors; Titration
• ISSN: 2624-8549; 2624-8549
• DOI: 10.3390/chemistry4040092

A simple and cost-effective optical sensing system based on quinizarin fluorescent dye (QZ) for the selective and reversible sensing of CH3COO− anions is reported. The anion binding affinity of QZ towards different anions was monitored using electronic absorption and fluorescence emission titration studies in DMSO. The UV-visible absorption spectrum of QZ showed a decrease in the intensity of the characteristic absorption peaks at λ = 280, 323, and 475 nm, while a new peak appeared at λ = 586 nm after the addition of CH3COO− anions. Similarly, the initial strong emission intensity of QZ was attenuated following titration with CH3COO− anions. Notably, similar titration using other anions, such as F−, Cl−, I−, NO3−, NO2−, and H2PO4-, caused no observable changes in both absorption and emission spectra. The selective sensing of CH3COO− anions was also reflected by a sharp visual color change from bright green to faint green under room light. Further, the binding was found to be reversible, and this makes QZ a potential optical and colorimetric sensor for selective, reversible, and ppb-level detection of CH3COO− anions in a DMSO medium.