Carbon Allotropes-Based Paints and Their Composite Coatings for Electromagnetic Shielding Applications

• Published in: Nanomaterials (Basel, Switzerland) Switzerland), 2022-05, Vol.12 (11), p.1839
• Main Authors: Tudose, Ioan Valentin, Mouratis, Kyriakos, Ionescu, Octavian Narcis, Romanitan, Cosmin, Pachiu, Cristina, Pricop, Emil, Khomenko, Volodymyr H, Butenko, Oksana, Chernysh, Oksana, Barsukov, Viacheslav Z, Suchea, Mirela Petruta, Koudoumas, Emmanouel
• Format: Article
• Language: English
• Subjects: Air temperature; alcohol-based conductive paints; Allotropy; Black carbon; Carbon; Carbon black; carbon-based materials; Coatings; Composite materials; Dielectric properties; Drying; Electrical conductivity; Electrical resistivity; Electromagnetic interference; Electromagnetic radiation; Electromagnetic shielding; Electronic equipment; EMI shielding applications; Environmental testing; Formulations; Graphene; Graphite; Iron compounds; Iron ores; Iron oxides; Mixtures; multicomponent nanocomposites; Nanocomposites; Paints; Physical characteristics; Protective coatings; Radiation; Room temperature; Scanning electron microscopy; Thickness; Visibility
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano12111839

The present manuscript reports on optimized formulations of alcohol-based conductive paints for electromagnetic interference shielding (EMI), which can ensure compatibility and reduce the visibility of electronic equipment, as a continuation of our previous work in this field, which examined water-based formulations for other applications. Graphite, carbon black, graphene, Fe O , Fe ore, and PEDOT:PSS in various ratios and combinations were employed in an alcohol base for developing homogeneous paint-like fluid mixtures that could be easily applied to surfaces with a paintbrush, leading to homogeneous, uniform, opaque layers, drying fast in the air at room temperature; these layers had a reasonably good electrical conductivity and, subsequently, an efficient EMI-shielding performance. Uniform, homogeneous and conductive layers with a thickness of over 1 mm without exfoliations and cracking were prepared with the developed paints, offering an attenuation of up to 50 dB of incoming GHz electromagnetic radiation. The structural and morphological characteristics of the paints, which were studied in detail, indicated that these are not simple physical mixtures of the ingredients but new composite materials. Finally, mechano-climatic and environmental tests on the coatings demonstrated their quality, since temperature, humidity and vibration stressors did not affect them; this result proves that these coatings are suitable for commercial products.