Thermoplastic Composite Materials Approach for More Circular Components: From Monomer to In Situ Polymerization, a Review

• Published in: Journal of composites science 2022-05, Vol.6 (5), p.132
• Main Authors: Valente, Marco, Rossitti, Ilaria, Biblioteca, Ilario, Sambucci, Matteo
• Format: Article
• Language: English
• Subjects: anionic polyamide 6; Anionic polymerization; Caprolactam; casting; Chemical properties; composite LCA; Composite materials; Crystallization; Environmental impact; Fiber composites; Glass fiber reinforced plastics; High density polyethylenes; Investigations; Life cycle assessment; Moisture absorption; Molecular weight; Monomers; Nylon 6; Optimization; Polymer matrix composites; Polymer melts; Polymerization; Process parameters; Thermoplastic composites; thermoplastic resin; Thermoplastic resins; vacuum infusion; Viscosity
• ISSN: 2504-477X; 2504-477X
• DOI: 10.3390/jcs6050132

To move toward eco-sustainable and circular composites, one of the most effective solutions is to create thermoplastic composites. The strong commitment of world organizations in the field of safeguarding the planet has directed the research of these materials toward production processes with a lower environmental impact and a strong propensity to recycle the polymeric part. Under its chemical properties, Nylon 6 is the polymer that best satisfies this specific trade-off. The most common production processes that use a thermosetting matrix are described. Subsequently, the work aimed at investigating the use of thermoplastics in the same processes to obtain comparable performances with the materials that are currently used. Particular attention was given to the in situ anionic polymerization process of Nylon 6, starting from the ε-caprolactam monomer. The dependencies of the process parameters, such as temperature, time, pressure, humidity, and concentration of initiators and activators, were therefore investigated with reference to the vacuum infusion technique, currently optimized only to produce thermosetting matrix composites, but promising for the realization of thermoplastic matrix composite; this is the reason why we chose to focus our attention on the vacuum infusion. Finally, three production processes of the polymeric matrix and glass fiber composites were compared in terms of carbon footprint and cumulative energy demand (CED) through life-cycle assessment (LCA).