Cost-effective production of radiation shielding coatings using multilayers of titania and silica

• Published in: Results in optics 2023-12, Vol.13, p.100559, Article 100559
• Main Authors: Yepuri, Venkatesh, Balamurugan, K.
• Format: Article
• Language: English
• Subjects: Five-layer; Infrared Reflection; Spin coating; Thermal insulation; TiO2/SiO2; Visible light reflection
• ISSN: 2666-9501; 2666-9501
• DOI: 10.1016/j.rio.2023.100559

The presence of visible and infrared (IR) radiations available from solar radiation causes the temperature in the atmosphere to rise. Because of the temperature disparity, glass-walled buildings typically utilize air conditioners, increasing the generation of green-house gases in the environment. As a result, the application of reflection coating is required to safeguard the environment and limit the danger of greenhouse emissions. We present here the fabrication of a thermal insulating coating utilizing a multilayer TiO2/SiO2 structure that can reflect visible and infrared light with fewer layers of the aforementioned combination. X-ray diffraction was used to examine the as-fabricated structure on the glass substrate and found the anatase phase of TiO2 with the strongest peak at Bragg angle 25O. Fourier transform infrared spectroscopy was used to investigate the presence of TiO2 and SiO2 functional linkages, which were found at 904 cm−1, and 763 cm−1 wavenumbers respectively. Cross-sectional field emission scanning electron microscopy examinations on the fabricated five-layer (TiO2/SiO2/TiO2/SiO2/TiO2) multilayer structure revealed the presence of TiO2 and SiO2 with thicknesses calculated around 186/300/273/218/131 nm respectively. Furthermore, reflectance analysis on the as-fabricated multilayer structure demonstrated 90 % reflectance in the infrared spectral region, and 100 % in the visible region. As a result, developed coatings for glass furnishings were advised in order to not only deflect visible and infrared radiations from the sun spectrum and keep indoor temperatures cool without the use of air conditioners, but also to act as visible light communication boosters.