3,4,7,8-Tetramethyl-1,10-phenanthrolin-1-ium nitrate monohydrate

In the crystal of the title compound, C 16 H 17 N 2 + ·NO 3 − ·H 2 O, the tetramethyl-1,10-phenanthrolinium cations, nitrate anions and lattice water molecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-06, Vol.68 (6), p.o1931-o1932
Main Authors: Zhang, Ke-Jie, Zhang, Yan-Fang
Format: Article
Language:English
Online Access:Get full text
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Summary:In the crystal of the title compound, C 16 H 17 N 2 + ·NO 3 − ·H 2 O, the tetramethyl-1,10-phenanthrolinium cations, nitrate anions and lattice water molecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation, anion and water molecule are linked by O—H...O and N—H...O hydrogen bonds into a sheet parallel to the bc plane. π–π stacking between phenanthroline ring systems is observed in the crystal structure, the centroid–centroid distance being 3.4745 (6) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812023318