Removal Performance and Mechanism of Emerging Pollutant Chloroquine Phosphate from Water by Iron and Magnesium Co-Modified Rape Straw Biochar

• Published in: Molecules (Basel, Switzerland) Switzerland), 2023-04, Vol.28 (8), p.3290
• Main Authors: Sun, Hongwei, He, Jinjin, Liu, Yucan, Ji, Xianguo, Wang, Gang, Yang, Xiaoyong, Zhang, Yanxiang
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; adsorption mechanism; Agricultural wastes; Aqueous solutions; biochar; Charcoal; Charcoal - chemistry; Chemical properties; Chloroquine; chloroquine phosphate; Coronaviruses; COVID-19; COVID-19 Drug Treatment; Efficiency; Electrostatic properties; Environmental aspects; Environmental hazards; Environmental Pollutants - analysis; Fe/Mg; Humans; Hydrogen bonding; Ionic strength; Iron; Iron - chemistry; Kinetics; Magnesium; modification; Organic contaminants; Oxidation; Pollutant removal; Pollutants; Purification; Rape (Plant); Severe acute respiratory syndrome; Straw; Synergistic effect; Water; Water Pollutants, Chemical - chemistry; Water pollution
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules28083290

Chloroquine phosphate (CQP) is effective in treating coronavirus disease 2019 (COVID-19); thus, its usage is rapidly increasing, which may pose a potential hazard to the environment and living organisms. However, there are limited findings on the removal of CQP in water. Herein, iron and magnesium co-modified rape straw biochar (Fe/Mg-RSB) was prepared to remove CQP from the aqueous solution. The results showed that Fe and Mg co-modification enhanced the adsorption efficiency of rape straw biochar (RSB) for CQP with the maximum adsorption capacity of 42.93 mg/g (at 308 K), which was about two times higher than that of RSB. The adsorption kinetics and isotherms analysis, as well as the physicochemical characterization analysis, demonstrated that the adsorption of CQP onto Fe/Mg-RSB was caused by the synergistic effect of pore filling, π-π interaction, hydrogen bonding, surface complexation, and electrostatic interaction. In addition, although solution pH and ionic strength affected the adsorption performance of CQP, Fe/Mg-RSB still had a high adsorption capability for CQP. Column adsorption experiments revealed that the Yoon-Nelson model better described the dynamic adsorption behavior of Fe/Mg-RSB. Furthermore, Fe/Mg-RSB had the potential for repeated use. Therefore, Fe and Mg co-modified biochar could be used for the remediation of CQP from contaminated water.