Crystal structure of triphenyl(quinolin-8-olato)tin(IV)

Triphenyl(quinolin-8-olato)tin crystallizes as two symmetry-independent molecules whose metal atoms both exist in a cis-C3SnNO trigonal bipyramidal coordination polyhedron that is 29 % distorted toward a square pyramid. The crystal structure [orthorhombic Pbcn space group], with a 26.701(2), b 10.35...

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Bibliographic Details
Published in:Macedonian Journal of Chemistry and Chemical Engineering 2009-01, Vol.28 (2), p.169-171
Main Authors: Amini, Mostafa M., Azadmeher, Amirreza, Khavasi, Hamid Reza, Ng, Seik Weng
Format: Article
Language:English
Subjects:
crystal structure
triphenyl(quinolin-8-olato)tin
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Summary:Triphenyl(quinolin-8-olato)tin crystallizes as two symmetry-independent molecules whose metal atoms both exist in a cis-C3SnNO trigonal bipyramidal coordination polyhedron that is 29 % distorted toward a square pyramid. The crystal structure [orthorhombic Pbcn space group], with a 26.701(2), b 10.3555(6), c 31.322(2) Å; V 8660.5(9) Å3] is refined from 5950 I > 2σ(I) Mo–Kα reflections measured at 200 K to an R-index of 0.050.
ISSN:1857-5552
1857-5625
DOI:10.20450/mjcce.2009.207