Crystal structure and Hirshfeld surface analysis of ( E )-1-[2,2-di-chloro-1-(4-nitro-phen-yl)ethen-yl]-2-(4-fluoro-phen-yl)diazene

In the title compound, C H Cl FN O , the 4-fluoro-phenyl ring and the nitro-substituted benzene ring form a dihedral angle of 63.29 (8)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds into chains running parallel to the axis. The crystal packing is further stabilized by C-Cl⋯π, C-F⋯π...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2019-02, Vol.75 (Pt 2), p.237-241
Main Authors: Atioğlu, Zeliha, Akkurt, Mehmet, Shikhaliyev, Namiq Q, Suleymanova, Gulnar T, Bagirova, Khanim N, Toze, Flavien A A
Format: Article
Language:English
Subjects:
4-fluorophenyl ring
crystal structure
Hirshfeld surface analysis
hydrogen bonding
nitro-substituted benzene ring
Research Communications
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Summary:In the title compound, C H Cl FN O , the 4-fluoro-phenyl ring and the nitro-substituted benzene ring form a dihedral angle of 63.29 (8)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds into chains running parallel to the axis. The crystal packing is further stabilized by C-Cl⋯π, C-F⋯π and N-O⋯π inter-actions. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯O/O⋯H (15.5%), H⋯H (15.3%), Cl⋯H/H⋯Cl (13.8%), C⋯H/H⋯C (9.5%) and F⋯H/H⋯F (8.2%) inter-actions.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989019000707