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Cation-doping effects on the conductivities of the mayenite Ca12Al14O33
The mayenite Ca Al material, owing to its oxide ion conducting behavior and the low cost of raw materials, has the potential of being applied in solid oxide fuel cells as an electrolyte. However, suffering from the relatively low oxide ion conductivity, there is still a long way to go for its practi...
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| Published in: | High temperature materials and processes 2023-11, Vol.42 (1), p.pp. 690-694 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 694 |
| container_issue | 1 |
| container_start_page | pp. 690 |
| container_title | High temperature materials and processes |
| container_volume | 42 |
| creator | Song, Xingping Guo, Yaqiong Chen, Wenzhuo Hou, Keke Duan, Xiaoxu Xu, Jungu |
| description | The mayenite Ca
Al
material, owing to its oxide ion conducting behavior and the low cost of raw materials, has the potential of being applied in solid oxide fuel cells as an electrolyte. However, suffering from the relatively low oxide ion conductivity, there is still a long way to go for its practical application. To enhance the oxide ion conduction in Ca
Al
, many efforts have been endowed to this from different research groups but hardly succeeded. In this work, the Ca
Al
-based materials with Y, In, and Cu-doping on the Ca or Al sites were fabricated through a traditional solid-state reaction method (for Y-doping on Ca and Cu-doping on Al) or a glass-crystallization method (for In-doping on Al), with their electrical conductivities being studied. The results revealed that the solid solution regions of Ca
Al
, Ca
Al
In
, and Ca
Al
Cu
were 0 ≤
≤ 0.15, 0 ≤
≤ 0.1, and 0 ≤
≤ 0.3, respectively. The electrical conductivities of all these doped materials were investigated. |
| doi_str_mv | 10.1515/htmp-2022-0295 |
| format | article |
| fullrecord | <record><control><sourceid>walterdegruyter_doaj_</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_7109a798bdc24c449fc2a17521a30ea4</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_7109a798bdc24c449fc2a17521a30ea4</doaj_id><sourcerecordid>10_1515_htmp_2022_0295421</sourcerecordid><originalsourceid>FETCH-LOGICAL-d311t-2115d6807af933b375dcd080f1bd03a8ef87a7296a066bf45e904eb59bd65f8a3</originalsourceid><addsrcrecordid>eNotkE1rwkAQQJdCoWK99pw_kHZnP7LZo0hrBcFLe14m-6ErMSvJ2uK_b6Kdywzv8GAeIS9AX0GCfDvk07lklLGSMi0fyIyBhpJyJp7IYhiOdByhQSqYkfUKc0xd6dI5dvvCh-BtHorUFfngC5s6d7E5_sQc_UjDjZ7w6ruYfbFCYMsWxI7zZ_IYsB384n_PyffH-9fqs9zu1pvVcls6DpBLBiBdVVOFQXPecCWddbSmARpHOdY-1AoV0xXSqmqCkF5T4RupG1fJUCOfk83d6xIezbmPJ-yvJmE0N5D6vcE-R9t6o4BqVLpunGXCCqGDZQhKMkBOPYrRpe-uX2yz753f95freJhjuvTd-IUBaqaiZipqpqJmKioY8D_g42to</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Cation-doping effects on the conductivities of the mayenite Ca12Al14O33</title><source>Walter De Gruyter: Open Access Journals</source><creator>Song, Xingping ; Guo, Yaqiong ; Chen, Wenzhuo ; Hou, Keke ; Duan, Xiaoxu ; Xu, Jungu</creator><creatorcontrib>Song, Xingping ; Guo, Yaqiong ; Chen, Wenzhuo ; Hou, Keke ; Duan, Xiaoxu ; Xu, Jungu</creatorcontrib><description>The mayenite Ca
Al
material, owing to its oxide ion conducting behavior and the low cost of raw materials, has the potential of being applied in solid oxide fuel cells as an electrolyte. However, suffering from the relatively low oxide ion conductivity, there is still a long way to go for its practical application. To enhance the oxide ion conduction in Ca
Al
, many efforts have been endowed to this from different research groups but hardly succeeded. In this work, the Ca
Al
-based materials with Y, In, and Cu-doping on the Ca or Al sites were fabricated through a traditional solid-state reaction method (for Y-doping on Ca and Cu-doping on Al) or a glass-crystallization method (for In-doping on Al), with their electrical conductivities being studied. The results revealed that the solid solution regions of Ca
Al
, Ca
Al
In
, and Ca
Al
Cu
were 0 ≤
≤ 0.15, 0 ≤
≤ 0.1, and 0 ≤
≤ 0.3, respectively. The electrical conductivities of all these doped materials were investigated.</description><identifier>EISSN: 2191-0324</identifier><identifier>DOI: 10.1515/htmp-2022-0295</identifier><language>eng</language><publisher>De Gruyter</publisher><subject>cation-doping ; conductivity ; high temperature solid oxide fuel cells ; mayenite Ca ; mayenite ca12al14o33 ; oxide ion conductors</subject><ispartof>High temperature materials and processes, 2023-11, Vol.42 (1), p.pp. 690-694</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.degruyter.com/document/doi/10.1515/htmp-2022-0295/pdf$$EPDF$$P50$$Gwalterdegruyter$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.degruyter.com/document/doi/10.1515/htmp-2022-0295/html$$EHTML$$P50$$Gwalterdegruyter$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,27924,27925,67158,68942</link.rule.ids></links><search><creatorcontrib>Song, Xingping</creatorcontrib><creatorcontrib>Guo, Yaqiong</creatorcontrib><creatorcontrib>Chen, Wenzhuo</creatorcontrib><creatorcontrib>Hou, Keke</creatorcontrib><creatorcontrib>Duan, Xiaoxu</creatorcontrib><creatorcontrib>Xu, Jungu</creatorcontrib><title>Cation-doping effects on the conductivities of the mayenite Ca12Al14O33</title><title>High temperature materials and processes</title><description>The mayenite Ca
Al
material, owing to its oxide ion conducting behavior and the low cost of raw materials, has the potential of being applied in solid oxide fuel cells as an electrolyte. However, suffering from the relatively low oxide ion conductivity, there is still a long way to go for its practical application. To enhance the oxide ion conduction in Ca
Al
, many efforts have been endowed to this from different research groups but hardly succeeded. In this work, the Ca
Al
-based materials with Y, In, and Cu-doping on the Ca or Al sites were fabricated through a traditional solid-state reaction method (for Y-doping on Ca and Cu-doping on Al) or a glass-crystallization method (for In-doping on Al), with their electrical conductivities being studied. The results revealed that the solid solution regions of Ca
Al
, Ca
Al
In
, and Ca
Al
Cu
were 0 ≤
≤ 0.15, 0 ≤
≤ 0.1, and 0 ≤
≤ 0.3, respectively. The electrical conductivities of all these doped materials were investigated.</description><subject>cation-doping</subject><subject>conductivity</subject><subject>high temperature solid oxide fuel cells</subject><subject>mayenite Ca</subject><subject>mayenite ca12al14o33</subject><subject>oxide ion conductors</subject><issn>2191-0324</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNotkE1rwkAQQJdCoWK99pw_kHZnP7LZo0hrBcFLe14m-6ErMSvJ2uK_b6Kdywzv8GAeIS9AX0GCfDvk07lklLGSMi0fyIyBhpJyJp7IYhiOdByhQSqYkfUKc0xd6dI5dvvCh-BtHorUFfngC5s6d7E5_sQc_UjDjZ7w6ruYfbFCYMsWxI7zZ_IYsB384n_PyffH-9fqs9zu1pvVcls6DpBLBiBdVVOFQXPecCWddbSmARpHOdY-1AoV0xXSqmqCkF5T4RupG1fJUCOfk83d6xIezbmPJ-yvJmE0N5D6vcE-R9t6o4BqVLpunGXCCqGDZQhKMkBOPYrRpe-uX2yz753f95freJhjuvTd-IUBaqaiZipqpqJmKioY8D_g42to</recordid><startdate>20231110</startdate><enddate>20231110</enddate><creator>Song, Xingping</creator><creator>Guo, Yaqiong</creator><creator>Chen, Wenzhuo</creator><creator>Hou, Keke</creator><creator>Duan, Xiaoxu</creator><creator>Xu, Jungu</creator><general>De Gruyter</general><scope>DOA</scope></search><sort><creationdate>20231110</creationdate><title>Cation-doping effects on the conductivities of the mayenite Ca12Al14O33</title><author>Song, Xingping ; Guo, Yaqiong ; Chen, Wenzhuo ; Hou, Keke ; Duan, Xiaoxu ; Xu, Jungu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-d311t-2115d6807af933b375dcd080f1bd03a8ef87a7296a066bf45e904eb59bd65f8a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>cation-doping</topic><topic>conductivity</topic><topic>high temperature solid oxide fuel cells</topic><topic>mayenite Ca</topic><topic>mayenite ca12al14o33</topic><topic>oxide ion conductors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Song, Xingping</creatorcontrib><creatorcontrib>Guo, Yaqiong</creatorcontrib><creatorcontrib>Chen, Wenzhuo</creatorcontrib><creatorcontrib>Hou, Keke</creatorcontrib><creatorcontrib>Duan, Xiaoxu</creatorcontrib><creatorcontrib>Xu, Jungu</creatorcontrib><collection>Directory of Open Access Journals</collection><jtitle>High temperature materials and processes</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Song, Xingping</au><au>Guo, Yaqiong</au><au>Chen, Wenzhuo</au><au>Hou, Keke</au><au>Duan, Xiaoxu</au><au>Xu, Jungu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cation-doping effects on the conductivities of the mayenite Ca12Al14O33</atitle><jtitle>High temperature materials and processes</jtitle><date>2023-11-10</date><risdate>2023</risdate><volume>42</volume><issue>1</issue><spage>pp. 690</spage><epage>694</epage><pages>pp. 690-694</pages><eissn>2191-0324</eissn><abstract>The mayenite Ca
Al
material, owing to its oxide ion conducting behavior and the low cost of raw materials, has the potential of being applied in solid oxide fuel cells as an electrolyte. However, suffering from the relatively low oxide ion conductivity, there is still a long way to go for its practical application. To enhance the oxide ion conduction in Ca
Al
, many efforts have been endowed to this from different research groups but hardly succeeded. In this work, the Ca
Al
-based materials with Y, In, and Cu-doping on the Ca or Al sites were fabricated through a traditional solid-state reaction method (for Y-doping on Ca and Cu-doping on Al) or a glass-crystallization method (for In-doping on Al), with their electrical conductivities being studied. The results revealed that the solid solution regions of Ca
Al
, Ca
Al
In
, and Ca
Al
Cu
were 0 ≤
≤ 0.15, 0 ≤
≤ 0.1, and 0 ≤
≤ 0.3, respectively. The electrical conductivities of all these doped materials were investigated.</abstract><pub>De Gruyter</pub><doi>10.1515/htmp-2022-0295</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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| identifier | EISSN: 2191-0324 |
| ispartof | High temperature materials and processes, 2023-11, Vol.42 (1), p.pp. 690-694 |
| issn | 2191-0324 |
| language | eng |
| recordid | cdi_doaj_primary_oai_doaj_org_article_7109a798bdc24c449fc2a17521a30ea4 |
| source | Walter De Gruyter: Open Access Journals |
| subjects | cation-doping conductivity high temperature solid oxide fuel cells mayenite Ca mayenite ca12al14o33 oxide ion conductors |
| title | Cation-doping effects on the conductivities of the mayenite Ca12Al14O33 |
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