Cyclic phosphonium ionic liquids

Ionic liquids (ILs) incorporating cyclic phosphonium cations are a novel category of materials. We report here on the synthesis and characterization of four new cyclic phosphonium bis(trifluoromethylsulfonyl)amide ILs with aliphatic and aromatic pendant groups. In addition to the syntheses of these...

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Published in:Beilstein journal of organic chemistry 2014-01, Vol.10 (1), p.271-275
Main Authors: Lall-Ramnarine, Sharon I, Mukhlall, Joshua A, Wishart, James F, Engel, Robert R, Romeo, Alicia R, Gohdo, Masao, Ramati, Sharon, Berman, Marc, Suarez, Sophia N
Format: Article
Language:English
Subjects:
Chemistry
cyclic phosphonium
Full Research Paper
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ionic liquid
organophosphorus
phosphinanium
phospholanium
phosphonium
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cited_by cdi_FETCH-LOGICAL-c471t-f1f7061d637b5d79118ddf70c47db83f13bfb47a4c852d1690879d0104a27d093
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container_title Beilstein journal of organic chemistry
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creator Lall-Ramnarine, Sharon I
Mukhlall, Joshua A
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Ramati, Sharon
Berman, Marc
Suarez, Sophia N
description Ionic liquids (ILs) incorporating cyclic phosphonium cations are a novel category of materials. We report here on the synthesis and characterization of four new cyclic phosphonium bis(trifluoromethylsulfonyl)amide ILs with aliphatic and aromatic pendant groups. In addition to the syntheses of these novel materials, we report on a comparison of their properties with their ammonium congeners. These exemplars are slightly less conductive and have slightly smaller self-diffusion coefficients than their cyclic ammonium congeners.
doi_str_mv 10.3762/bjoc.10.22
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subjects Chemistry
cyclic phosphonium
Full Research Paper
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ionic liquid
organophosphorus
phosphinanium
phospholanium
phosphonium
title Cyclic phosphonium ionic liquids
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