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Tunability of Photovoltaic Functions via Halogen Substitution [(Ade) 2 CdX 4 ](X = Cl, Br): A Class of Three-Dimensional Organic-Inorganic Hybrid Materials
Two new three-dimensional organic-inorganic hybrid crystalline materials, [(Ade) CdCl ] ( ) and [(Ade) CdBr ] ( ), were obtained by the slow evaporation of adenine (Ade) and cadmium chloride in aqueous solution at room temperature with hydrochloric acid and hydrobromic acid used as halogen sources....
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| Published in: | Molecules (Basel, Switzerland) Switzerland), 2024-06, Vol.29 (12), p.2773 |
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| container_title | Molecules (Basel, Switzerland) |
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| creator | Lv, Meixia Hu, Hongzhi Adila, Abuduheni Yan, Yibo Liu, Yang Liu, Zunqi |
| description | Two new three-dimensional organic-inorganic hybrid crystalline materials, [(Ade)
CdCl
] (
) and [(Ade)
CdBr
] (
), were obtained by the slow evaporation of adenine (Ade) and cadmium chloride in aqueous solution at room temperature with hydrochloric acid and hydrobromic acid used as halogen sources. The structural, thermal, optical, and electrical properties were characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, variable-temperature-variable-frequency dielectric constant analysis, and electrochemical tests. With increasing the substitution of Cl by Br, the composition of the material changed and the space group shifted from
-1 to
2
/m, with a significant blue-shift in the fluorescence emission. Changing the temperature induced the deformation of the three-dimensional framework structure formed by hydrogen bonding interactions, leading to dielectric anomalies. Cyclic voltammetry tests showed the good reversibility of the electrolysis process. The structural diversity of the complexes was realized by modulating the halogen composition, and a new method for designing novel organic-inorganic hybrids with controllable photoelectric functionality was proposed. |
| doi_str_mv | 10.3390/molecules29122773 |
| format | article |
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CdCl
] (
) and [(Ade)
CdBr
] (
), were obtained by the slow evaporation of adenine (Ade) and cadmium chloride in aqueous solution at room temperature with hydrochloric acid and hydrobromic acid used as halogen sources. The structural, thermal, optical, and electrical properties were characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, variable-temperature-variable-frequency dielectric constant analysis, and electrochemical tests. With increasing the substitution of Cl by Br, the composition of the material changed and the space group shifted from
-1 to
2
/m, with a significant blue-shift in the fluorescence emission. Changing the temperature induced the deformation of the three-dimensional framework structure formed by hydrogen bonding interactions, leading to dielectric anomalies. Cyclic voltammetry tests showed the good reversibility of the electrolysis process. The structural diversity of the complexes was realized by modulating the halogen composition, and a new method for designing novel organic-inorganic hybrids with controllable photoelectric functionality was proposed.</description><identifier>ISSN: 1420-3049</identifier><identifier>EISSN: 1420-3049</identifier><identifier>DOI: 10.3390/molecules29122773</identifier><identifier>PMID: 38930838</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Cadmium ; Chlorine ; dielectric ; electrochemical ; Electrolysis ; Hydrogen ; Hydrogen bonding ; Hydrogen bonds ; metal halide ; Nucleic acids ; Phase transitions ; photoluminescence ; Solar energy industry ; Temperature ; three-dimensional framework</subject><ispartof>Molecules (Basel, Switzerland), 2024-06, Vol.29 (12), p.2773</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/3072619444/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/3072619444?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,25753,27924,27925,37012,44590,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38930838$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lv, Meixia</creatorcontrib><creatorcontrib>Hu, Hongzhi</creatorcontrib><creatorcontrib>Adila, Abuduheni</creatorcontrib><creatorcontrib>Yan, Yibo</creatorcontrib><creatorcontrib>Liu, Yang</creatorcontrib><creatorcontrib>Liu, Zunqi</creatorcontrib><title>Tunability of Photovoltaic Functions via Halogen Substitution [(Ade) 2 CdX 4 ](X = Cl, Br): A Class of Three-Dimensional Organic-Inorganic Hybrid Materials</title><title>Molecules (Basel, Switzerland)</title><addtitle>Molecules</addtitle><description>Two new three-dimensional organic-inorganic hybrid crystalline materials, [(Ade)
CdCl
] (
) and [(Ade)
CdBr
] (
), were obtained by the slow evaporation of adenine (Ade) and cadmium chloride in aqueous solution at room temperature with hydrochloric acid and hydrobromic acid used as halogen sources. The structural, thermal, optical, and electrical properties were characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, variable-temperature-variable-frequency dielectric constant analysis, and electrochemical tests. With increasing the substitution of Cl by Br, the composition of the material changed and the space group shifted from
-1 to
2
/m, with a significant blue-shift in the fluorescence emission. Changing the temperature induced the deformation of the three-dimensional framework structure formed by hydrogen bonding interactions, leading to dielectric anomalies. Cyclic voltammetry tests showed the good reversibility of the electrolysis process. The structural diversity of the complexes was realized by modulating the halogen composition, and a new method for designing novel organic-inorganic hybrids with controllable photoelectric functionality was proposed.</description><subject>Cadmium</subject><subject>Chlorine</subject><subject>dielectric</subject><subject>electrochemical</subject><subject>Electrolysis</subject><subject>Hydrogen</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>metal halide</subject><subject>Nucleic acids</subject><subject>Phase transitions</subject><subject>photoluminescence</subject><subject>Solar energy industry</subject><subject>Temperature</subject><subject>three-dimensional framework</subject><issn>1420-3049</issn><issn>1420-3049</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNpNkVtrFDEUxwdRbK1-AF8k4EsLTs1tcin4sK7WXahUcIWCyHAmyWyzzE5qkinsZ_HLmnWryHk4f87lx7lU1UuCzxnT-O02DM5Mg0tUE0qlZI-qY8Iprhnm-vF_-qh6ltIGY0o4aZ5WR0xphhVTx9Wv1TRC5wefdyj06MttyOE-DBm8QZfTaLIPY0L3HtAChrB2I_o6dSn7PO0z6PvpzLozRNHc3iCOfpzeoHdoPrxB7-PZBZoVCSntwavb6Fz9wW_dmEojDOg6rmH0pl6O4aDQYtdFb9FnyC56GNLz6klfnHvx4E-qb5cfV_NFfXX9aTmfXdWWKp5r6rDUpCdWGdH3hnWWK6Uo2EZ3jRYMF6UaJ7AkVlAujNVUkabHwDpChGEn1fLAtQE27V30W4i7NoBv_wTKeC3E7M3gWkm0sL1ljQXMudTKgpINl7hcVAnqCuv1gXUXw8_JpdxuwhTLvqllWFJBNOe8VJ0fqtZQoH7sQ45gilm39SaMrvclPpNaCyJ0s2949YCduq2z_4b8-0j2G8R2nnQ</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Lv, Meixia</creator><creator>Hu, Hongzhi</creator><creator>Adila, Abuduheni</creator><creator>Yan, Yibo</creator><creator>Liu, Yang</creator><creator>Liu, Zunqi</creator><general>MDPI AG</general><scope>NPM</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>DOA</scope></search><sort><creationdate>20240601</creationdate><title>Tunability of Photovoltaic Functions via Halogen Substitution [(Ade) 2 CdX 4 ](X = Cl, Br): A Class of Three-Dimensional Organic-Inorganic Hybrid Materials</title><author>Lv, Meixia ; Hu, Hongzhi ; Adila, Abuduheni ; Yan, Yibo ; Liu, Yang ; Liu, Zunqi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-d284t-2e0791f1d8c6ffc3bd48882ad59b59630ad585e6071d6246cd92815f0a3b116c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Cadmium</topic><topic>Chlorine</topic><topic>dielectric</topic><topic>electrochemical</topic><topic>Electrolysis</topic><topic>Hydrogen</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>metal halide</topic><topic>Nucleic acids</topic><topic>Phase transitions</topic><topic>photoluminescence</topic><topic>Solar energy industry</topic><topic>Temperature</topic><topic>three-dimensional framework</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lv, Meixia</creatorcontrib><creatorcontrib>Hu, Hongzhi</creatorcontrib><creatorcontrib>Adila, Abuduheni</creatorcontrib><creatorcontrib>Yan, Yibo</creatorcontrib><creatorcontrib>Liu, Yang</creatorcontrib><creatorcontrib>Liu, Zunqi</creatorcontrib><collection>PubMed</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection (Proquest)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>PML(ProQuest Medical Library)</collection><collection>Publicly Available Content (ProQuest)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Directory of Open Access Journals</collection><jtitle>Molecules (Basel, Switzerland)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lv, Meixia</au><au>Hu, Hongzhi</au><au>Adila, Abuduheni</au><au>Yan, Yibo</au><au>Liu, Yang</au><au>Liu, Zunqi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tunability of Photovoltaic Functions via Halogen Substitution [(Ade) 2 CdX 4 ](X = Cl, Br): A Class of Three-Dimensional Organic-Inorganic Hybrid Materials</atitle><jtitle>Molecules (Basel, Switzerland)</jtitle><addtitle>Molecules</addtitle><date>2024-06-01</date><risdate>2024</risdate><volume>29</volume><issue>12</issue><spage>2773</spage><pages>2773-</pages><issn>1420-3049</issn><eissn>1420-3049</eissn><abstract>Two new three-dimensional organic-inorganic hybrid crystalline materials, [(Ade)
CdCl
] (
) and [(Ade)
CdBr
] (
), were obtained by the slow evaporation of adenine (Ade) and cadmium chloride in aqueous solution at room temperature with hydrochloric acid and hydrobromic acid used as halogen sources. The structural, thermal, optical, and electrical properties were characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, variable-temperature-variable-frequency dielectric constant analysis, and electrochemical tests. With increasing the substitution of Cl by Br, the composition of the material changed and the space group shifted from
-1 to
2
/m, with a significant blue-shift in the fluorescence emission. Changing the temperature induced the deformation of the three-dimensional framework structure formed by hydrogen bonding interactions, leading to dielectric anomalies. Cyclic voltammetry tests showed the good reversibility of the electrolysis process. The structural diversity of the complexes was realized by modulating the halogen composition, and a new method for designing novel organic-inorganic hybrids with controllable photoelectric functionality was proposed.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>38930838</pmid><doi>10.3390/molecules29122773</doi><oa>free_for_read</oa></addata></record> |
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| subjects | Cadmium Chlorine dielectric electrochemical Electrolysis Hydrogen Hydrogen bonding Hydrogen bonds metal halide Nucleic acids Phase transitions photoluminescence Solar energy industry Temperature three-dimensional framework |
| title | Tunability of Photovoltaic Functions via Halogen Substitution [(Ade) 2 CdX 4 ](X = Cl, Br): A Class of Three-Dimensional Organic-Inorganic Hybrid Materials |
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