Boron Doped Graphene Quantum Structure and MoS2 Nanohybrid as Anode Materials for Highly Reversible Lithium Storage

• Published in: Frontiers in chemistry 2019-03, Vol.7, p.116-116
• Main Authors: Riyanto, Sahroni, Imam, Bindumadhavan, Kartick, Chang, Pei-Yi, Doong, Ruey-an
• Format: Article
• Language: English
• Subjects: anode materials; boron-doped graphene quantum structures (BGQS); Chemistry; cycling stability; MoS2; reversible capacity
• ISSN: 2296-2646; 2296-2646
• DOI: 10.3389/fchem.2019.00116

Herein, the boron-doped graphene quantum structure (BGQS), which contains both the advantages of 0-D graphene quantum dot and 2-D reduced graphene oxide, has been fabricated by top-down hydrothermal method and then mixed with molybdenum sulfide (MoS 2 ) to serve as an active electrode material for the enhanced electrochemical performance of lithium ion battery. Results show that 30 wt% of BGQS/MoS 2 nanohybrid delivers the superior electrochemical performance in comparison with other BGQS/MoS 2 and bare components. A highly reversible capacity of 3,055 mAh g −1 at a current density of 50 mA g −1 is achieved for the initial discharge and a high reversible capacity of 1,041 mAh g −1 is obtained at 100 mA g −1 after 50 cycles. The improved electrochemical performance in BGQS/MoS 2 nanohybrid is attributed to the well exfoliated MoS 2 structures and the presence of BGQS, which can provide the vitally nano-dimensional contact for the enhanced electrochemical performance. Results obtained in this study clearly demonstrate that BGQS/MoS 2 is a promising material for lithium ion battery and can open a pathway to fabricate novel 2-D nanosheeted nanocomposites for highly reversible Li storage application.