Synthesis and Crystal Structure of 9-(4,6-dichloro-1,3,5-triazin-2-yl)-9H-carbazole

A carbazole-triazine hybrid was prepared by addition-elimination between carbazole and 2,4,6-trichlorotriazine in the presence of base. The compound shows intensely blue fluorescence both in solution and solid state when irradiated with UV-radiation. The structure of (3) was supported by the spectro...

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Bibliographic Details
Published in:Crystals (Basel) 2011-06, Vol.1 (2), p.28-33
Main Authors: Saeed, Aamer, Kazmi, Madiha, Samra, Shahid Ameen, Flörke, Ulrich
Format: Article
Language:English
Subjects:
carbazole-triazine hybrid
crystal structure
fluorescence
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Summary:A carbazole-triazine hybrid was prepared by addition-elimination between carbazole and 2,4,6-trichlorotriazine in the presence of base. The compound shows intensely blue fluorescence both in solution and solid state when irradiated with UV-radiation. The structure of (3) was supported by the spectroscopic data and unambiguously confirmed by the single crystal X-ray diffraction data. It was crystallized in the monoclinic space group C2/c with unit cell dimensions a = 20.280(3), b = 8.0726(14), c = 16.005(3) Å, α = γ = 90°, β = 98.947(3)°, V = 2588.3(8) ų, Z = 8.
ISSN:2073-4352
2073-4352
DOI:10.3390/cryst1020028