Monitoring kinetic and thermodynamic parameters of fluoride adsorption from aqueous solution by pks-based anion resins

Fluoride is important for human health, but high level of fluoride concentrations can be threatening for both humans and animals as well as damaging to the environment. This paper delineates on fluoride adsorption onto palm kernel shell-based anion resins under various fluoride concentrations and te...

Full description

Saved in:
Bibliographic Details
Published in:Journal of Mechanical Engineering and Sciences 2018-06, Vol.12 (2), p.3624-3632
Main Authors: Bashir, M.T., Salmiaton, A., Idris, A., Harun, R.
Format: Article
Language:English
Subjects:
Aqueous solutions
fluoride
kinetics
thermodynamics
palm kernel shells
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c397t-db9f9c8aa929b633558c8c846ad48dba7467fed1dac22abf0f2e969416ec37143
cites
container_end_page 3632
container_issue 2
container_start_page 3624
container_title Journal of Mechanical Engineering and Sciences
container_volume 12
creator Bashir, M.T.
Salmiaton, A.
Idris, A.
Harun, R.
description Fluoride is important for human health, but high level of fluoride concentrations can be threatening for both humans and animals as well as damaging to the environment. This paper delineates on fluoride adsorption onto palm kernel shell-based anion resins under various fluoride concentrations and temperatures. The equilibrium fluoride adsorption capacity demonstrated by the resins was observed 2.32 mg/g. Pseudo second-order model and Weber-Morris diffusion model were employed to evaluate the uptake rate and behavior of fluoride adsorption. The correlation coefficients (R2) between experimental data and pseudo second-order model predictions was almost unity at all concentrations (5, 10 and 15 mg/L), indicating goodness of fit of the model. On the other hand, the thermodynamic study revealed the endothermic nature of the process indicated by the positive value of enthalpy change (2.671 kJ/mol). Moreover, the process is dominantly physical in nature along with a slight contribution of chemisorption.
doi_str_mv 10.15282/jmes.12.2.2018.9.0321
format article
fullrecord <record><control><sourceid>proquest_doaj_</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_758c501c03d8463293c7298e973b3e8a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_758c501c03d8463293c7298e973b3e8a</doaj_id><sourcerecordid>2539544533</sourcerecordid><originalsourceid>FETCH-LOGICAL-c397t-db9f9c8aa929b633558c8c846ad48dba7467fed1dac22abf0f2e969416ec37143</originalsourceid><addsrcrecordid>eNo9kUFr3DAQhU1JoSHNXyiCnu1KGtmWjiUkaSCll_YsxtIo9WZtOZId2H8f7W4I76DhMfONhldV3wRvRCu1_LGbKDdCNkVc6MY0HKT4VF1KCaLWoPnFsdamVl1rvlTXOe845wKU5L2-rF5_x3lcYxrnJ_Y8zrSOjuHs2fqf0hT9YcapOAsmnGillFkMLOy3MuCJoc8xLesYZxZSnBi-bBS3zHLcbyd3OLDlOdcDZvIFe7QS5XHOX6vPAfeZrt_fq-rf3e3fm1_145_7h5ufj7UD06-1H0wwTiMaaYYOoG21K1IdeqX9gL3q-kBeeHRS4hB4kGQ6o0RHDnqh4Kp6OHN9xJ1d0jhhOtiIoz0ZMT1ZTOXmPdm-sFsuHAdfFoA04HppNJkeBiCNhfX9zFpSLIfm1e7ilubyfStbMK1SLUDp6s5dLsWcE4WPrYLbU2T2GJkV0haVyKyxx8jgDXlAjRI</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2539544533</pqid></control><display><type>article</type><title>Monitoring kinetic and thermodynamic parameters of fluoride adsorption from aqueous solution by pks-based anion resins</title><source>Publicly Available Content Database (Proquest) (PQ_SDU_P3)</source><creator>Bashir, M.T. ; Salmiaton, A. ; Idris, A. ; Harun, R.</creator><creatorcontrib>Bashir, M.T. ; Salmiaton, A. ; Idris, A. ; Harun, R. ; Department of Chemical and Environmental Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia ; Department of Civil Engineering, Qurtuba University of Science and Information Technology, Dera Ismail Khan, 29050, Pakistan</creatorcontrib><description>Fluoride is important for human health, but high level of fluoride concentrations can be threatening for both humans and animals as well as damaging to the environment. This paper delineates on fluoride adsorption onto palm kernel shell-based anion resins under various fluoride concentrations and temperatures. The equilibrium fluoride adsorption capacity demonstrated by the resins was observed 2.32 mg/g. Pseudo second-order model and Weber-Morris diffusion model were employed to evaluate the uptake rate and behavior of fluoride adsorption. The correlation coefficients (R2) between experimental data and pseudo second-order model predictions was almost unity at all concentrations (5, 10 and 15 mg/L), indicating goodness of fit of the model. On the other hand, the thermodynamic study revealed the endothermic nature of the process indicated by the positive value of enthalpy change (2.671 kJ/mol). Moreover, the process is dominantly physical in nature along with a slight contribution of chemisorption.</description><identifier>ISSN: 2289-4659</identifier><identifier>EISSN: 2231-8380</identifier><identifier>DOI: 10.15282/jmes.12.2.2018.9.0321</identifier><language>eng</language><publisher>Pekan: Universiti Malaysia Pahang</publisher><subject>Aqueous solutions ; fluoride; kinetics; thermodynamics; palm kernel shells</subject><ispartof>Journal of Mechanical Engineering and Sciences, 2018-06, Vol.12 (2), p.3624-3632</ispartof><rights>Per publisher notification this content is offered under CC BY © 2018. This work is published under https://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c397t-db9f9c8aa929b633558c8c846ad48dba7467fed1dac22abf0f2e969416ec37143</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2539544533?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,25753,27924,27925,37012,44590</link.rule.ids></links><search><creatorcontrib>Bashir, M.T.</creatorcontrib><creatorcontrib>Salmiaton, A.</creatorcontrib><creatorcontrib>Idris, A.</creatorcontrib><creatorcontrib>Harun, R.</creatorcontrib><creatorcontrib>Department of Chemical and Environmental Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia</creatorcontrib><creatorcontrib>Department of Civil Engineering, Qurtuba University of Science and Information Technology, Dera Ismail Khan, 29050, Pakistan</creatorcontrib><title>Monitoring kinetic and thermodynamic parameters of fluoride adsorption from aqueous solution by pks-based anion resins</title><title>Journal of Mechanical Engineering and Sciences</title><description>Fluoride is important for human health, but high level of fluoride concentrations can be threatening for both humans and animals as well as damaging to the environment. This paper delineates on fluoride adsorption onto palm kernel shell-based anion resins under various fluoride concentrations and temperatures. The equilibrium fluoride adsorption capacity demonstrated by the resins was observed 2.32 mg/g. Pseudo second-order model and Weber-Morris diffusion model were employed to evaluate the uptake rate and behavior of fluoride adsorption. The correlation coefficients (R2) between experimental data and pseudo second-order model predictions was almost unity at all concentrations (5, 10 and 15 mg/L), indicating goodness of fit of the model. On the other hand, the thermodynamic study revealed the endothermic nature of the process indicated by the positive value of enthalpy change (2.671 kJ/mol). Moreover, the process is dominantly physical in nature along with a slight contribution of chemisorption.</description><subject>Aqueous solutions</subject><subject>fluoride; kinetics; thermodynamics; palm kernel shells</subject><issn>2289-4659</issn><issn>2231-8380</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNo9kUFr3DAQhU1JoSHNXyiCnu1KGtmWjiUkaSCll_YsxtIo9WZtOZId2H8f7W4I76DhMfONhldV3wRvRCu1_LGbKDdCNkVc6MY0HKT4VF1KCaLWoPnFsdamVl1rvlTXOe845wKU5L2-rF5_x3lcYxrnJ_Y8zrSOjuHs2fqf0hT9YcapOAsmnGillFkMLOy3MuCJoc8xLesYZxZSnBi-bBS3zHLcbyd3OLDlOdcDZvIFe7QS5XHOX6vPAfeZrt_fq-rf3e3fm1_145_7h5ufj7UD06-1H0wwTiMaaYYOoG21K1IdeqX9gL3q-kBeeHRS4hB4kGQ6o0RHDnqh4Kp6OHN9xJ1d0jhhOtiIoz0ZMT1ZTOXmPdm-sFsuHAdfFoA04HppNJkeBiCNhfX9zFpSLIfm1e7ilubyfStbMK1SLUDp6s5dLsWcE4WPrYLbU2T2GJkV0haVyKyxx8jgDXlAjRI</recordid><startdate>20180601</startdate><enddate>20180601</enddate><creator>Bashir, M.T.</creator><creator>Salmiaton, A.</creator><creator>Idris, A.</creator><creator>Harun, R.</creator><general>Universiti Malaysia Pahang</general><general>Universiti Malaysia Pahang Publishing</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>DOA</scope></search><sort><creationdate>20180601</creationdate><title>Monitoring kinetic and thermodynamic parameters of fluoride adsorption from aqueous solution by pks-based anion resins</title><author>Bashir, M.T. ; Salmiaton, A. ; Idris, A. ; Harun, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c397t-db9f9c8aa929b633558c8c846ad48dba7467fed1dac22abf0f2e969416ec37143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aqueous solutions</topic><topic>fluoride; kinetics; thermodynamics; palm kernel shells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bashir, M.T.</creatorcontrib><creatorcontrib>Salmiaton, A.</creatorcontrib><creatorcontrib>Idris, A.</creatorcontrib><creatorcontrib>Harun, R.</creatorcontrib><creatorcontrib>Department of Chemical and Environmental Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia</creatorcontrib><creatorcontrib>Department of Civil Engineering, Qurtuba University of Science and Information Technology, Dera Ismail Khan, 29050, Pakistan</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Publicly Available Content Database (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Directory of Open Access Journals</collection><jtitle>Journal of Mechanical Engineering and Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bashir, M.T.</au><au>Salmiaton, A.</au><au>Idris, A.</au><au>Harun, R.</au><aucorp>Department of Chemical and Environmental Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia</aucorp><aucorp>Department of Civil Engineering, Qurtuba University of Science and Information Technology, Dera Ismail Khan, 29050, Pakistan</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Monitoring kinetic and thermodynamic parameters of fluoride adsorption from aqueous solution by pks-based anion resins</atitle><jtitle>Journal of Mechanical Engineering and Sciences</jtitle><date>2018-06-01</date><risdate>2018</risdate><volume>12</volume><issue>2</issue><spage>3624</spage><epage>3632</epage><pages>3624-3632</pages><issn>2289-4659</issn><eissn>2231-8380</eissn><abstract>Fluoride is important for human health, but high level of fluoride concentrations can be threatening for both humans and animals as well as damaging to the environment. This paper delineates on fluoride adsorption onto palm kernel shell-based anion resins under various fluoride concentrations and temperatures. The equilibrium fluoride adsorption capacity demonstrated by the resins was observed 2.32 mg/g. Pseudo second-order model and Weber-Morris diffusion model were employed to evaluate the uptake rate and behavior of fluoride adsorption. The correlation coefficients (R2) between experimental data and pseudo second-order model predictions was almost unity at all concentrations (5, 10 and 15 mg/L), indicating goodness of fit of the model. On the other hand, the thermodynamic study revealed the endothermic nature of the process indicated by the positive value of enthalpy change (2.671 kJ/mol). Moreover, the process is dominantly physical in nature along with a slight contribution of chemisorption.</abstract><cop>Pekan</cop><pub>Universiti Malaysia Pahang</pub><doi>10.15282/jmes.12.2.2018.9.0321</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 2289-4659
ispartof Journal of Mechanical Engineering and Sciences, 2018-06, Vol.12 (2), p.3624-3632
issn 2289-4659
2231-8380
language eng
recordid cdi_doaj_primary_oai_doaj_org_article_758c501c03d8463293c7298e973b3e8a
source Publicly Available Content Database (Proquest) (PQ_SDU_P3)
subjects Aqueous solutions
fluoride
kinetics
thermodynamics
palm kernel shells
title Monitoring kinetic and thermodynamic parameters of fluoride adsorption from aqueous solution by pks-based anion resins
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T11%3A11%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_doaj_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Monitoring%20kinetic%20and%20thermodynamic%20parameters%20of%20fluoride%20adsorption%20from%20aqueous%20solution%20by%20pks-based%20anion%20resins&rft.jtitle=Journal%20of%20Mechanical%20Engineering%20and%20Sciences&rft.au=Bashir,%20M.T.&rft.aucorp=Department%20of%20Chemical%20and%20Environmental%20Engineering,%20Universiti%20Putra%20Malaysia,%2043400%20UPM%20Serdang,%20Selangor,%20Malaysia&rft.date=2018-06-01&rft.volume=12&rft.issue=2&rft.spage=3624&rft.epage=3632&rft.pages=3624-3632&rft.issn=2289-4659&rft.eissn=2231-8380&rft_id=info:doi/10.15282/jmes.12.2.2018.9.0321&rft_dat=%3Cproquest_doaj_%3E2539544533%3C/proquest_doaj_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c397t-db9f9c8aa929b633558c8c846ad48dba7467fed1dac22abf0f2e969416ec37143%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2539544533&rft_id=info:pmid/&rfr_iscdi=true